ReviewACS central science2020
From Molecules to Porous Materials: Integrating Discrete Electrocatalytic Active Sites into Extended Frameworks.
Review in ACS central science, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 9 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
9 citing papers in PubMed.
- Using Host-Guest Chemistry to Examine the Effects of Porosity and Catalyst-Support Interactions on COAngewandte Chemie (International ed. in English) · 2025Article
- Mechanistic Insight into the Formation and Deposition of Conductive, Layered Metal-Organic Framework Nanocrystals.ACS nano · 2025Article
- Diffusional Electron Transport Coupled to Thermodynamically Driven Electron Transfers in Redox-Conductive Multivariate Metal-Organic Frameworks.Journal of the American Chemical Society · 2024Article
- Supramolecular Enhancement of Electrochemical Nitrate Reduction Catalyzed by Cobalt Porphyrin Organic Cages for Ammonia Electrosynthesis in Water.Angewandte Chemie (International ed. in English) · 2023Article
- Recent Developments on the Catalytic and Biosensing Applications of Porous Nanomaterials.Nanomaterials (Basel, Switzerland) · 2023Review
- Tuning Electrode Reactivity through Organometallic Complexes.ACS applied materials & interfaces · 2023Review
- Molecular Catalysis of Energy Relevance in Metal-Organic Frameworks: From Higher Coordination Sphere to System Effects.Chemical reviews · 2023Review
- Electrocatalytic water oxidation from a mixed linker MOF based on NU-1000 with an integrated ruthenium-based metallo-linker.Materials advances · 2022Article
- Mimicking the Electron Transport Chain and Active Site of [FeFe] Hydrogenases in One Metal-Organic Framework: Factors That Influence Charge Transport.Journal of the American Chemical Society · 2021Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
4 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Metal-organic and covalent-organic frameworks can serve as a bridge between the realms of homo- and heterogeneous catalytic systems. While there are numerous molecular complexes developed for electrocatalysis, homogeneous catalysts are hindered by slow catalyst diffusion, catalyst deactivation, and poor product yield. Heterogeneous catalysts can compensate for these shortcomings, yet they lack the synthetic and chemical tunability to promote rational design. To narrow this knowledge gap, there is a burgeoning field of framework-related research that incorporates molecular catalysts within porous architectures, resulting in an exceptional catalytic performance as compared to their molecular analogues. Framework materials provide structural stability to these catalysts, alter their electronic environments, and are easily tunable for increased catalytic activity. This Outlook compares molecular catalysts and corresponding framework materials to evaluate the effects of such integration on electrocatalytic performance. We describe several different classes of molecular motifs that have been included in framework materials and explore how framework design strategies improve on the catalytic behavior of their homogeneous counterparts. Finally, we will provide an outlook on new directions to drive fundamental research at the intersection of reticular-and electrochemistry.
Identifiers
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.