ArticlePolymers2020
Preferential Circularly Polarized Luminescence from a Nano-Segregated Liquid Crystalline Phase Using a Polymerized Twisted Nematic Platform.
Article in Polymers, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
2 citing papers in PubMed.
- Effect of Nematogen Doping in Bent-Core Molecular Systems with a Helical Nanofilament and Dark Conglomerate.Materials (Basel, Switzerland) · 2023Article
- Control of the Induced Handedness of Helical Nanofilaments Employing Cholesteric Liquid Crystal Fields.Molecules (Basel, Switzerland) · 2021Article
Corrections and comments
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Authors and funding
2 authors.
Funding
Abstract
In this study, a polymerized twisted nematic (TN) network was used as an extrinsic chiral platform to overcome the heterogeneity during spontaneous symmetry breaking in a mixed system comprising an achiral bent-core molecule and rod-like mesogen. The TN platform was prepared by photopolymerizing a reactive mesogen dispersed in a low molecular weight liquid crystal with TN orientation. The use of TN orientation to correct the degeneracy in bent-core molecular systems has been previously reported; however, to the best of our knowledge, this is the first study that uses an extrinsic chiral platform of a polymerized TN network. The heterogeneity in the nano-segregated phase of the achiral mixture was suppressed using the extrinsic TN platform with a twisted angle θ of ≥ |±30°|. When an achiral mixture doped with a luminescent guest molecule was refilled into the extrinsic chiral platform, preferential deracemization with one-handedness occurred, corresponding to the handedness of the TN platform. Therefore, circularly polarized luminescence with a preferential handedness can be achieved using this extrinsic chiral platform.
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