Evidence map›Paper›PMID 33124641›Full record

ArticleChemical communications (Cambridge, England)2020

Selective, cofactor-mediated catalytic oxidation of alkanethiols in a self-assembled cage host.

Bryce da Camara, Philip C Dietz, Kevin R Chalek, Leonard J Mueller, Richard J Hooley

Abstract read
In one paragraph

Article in Chemical communications (Cambridge, England), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Review
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

5 authors.

Bryce da CamaraDepartment of Chemistry and the UCR Center for Catalysis, University of California-Riverside, Riverside, CA 92521, USA. richard.hooley@ucr.edu.
Philip C Dietz
Kevin R Chalek
Leonard J Mueller
Richard J Hooley

Funding

Chemically-Rich Structure and Dynamics in the Active Site of Tryptophan SynthaseR01GM097569 · NIGMS · UNIVERSITY OF CALIFORNIA RIVERSIDE · PI MUELLER, LEONARD J · 2011 to 2020
$2.9M
NIGMS NIH HHS R01 GM097569
6 · The paper itself

Abstract

A spacious Fe(ii)-iminopyridine self-assembled cage complex can catalyze the oxidative dimerization of alkanethiols, with air as stoichiometric oxidant. The reaction is aided by selective molecular recognition of the reactants, and the active catalyst is derived from the Fe(ii) centers that provide the structural vertices of the host. The host is even capable of size-selective oxidation and can discriminate between alkanethiols of identical reactivity, based solely on size.

Identifiers

PMID33124641
PMCPMC7674236

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.