Evidence map›Paper›PMID 33110987›Full record

ArticleACS omega2020

Hybrid Pigments from Anthocyanin Analogues and Synthetic Clay Minerals.

Gustavo Thalmer M Silva, Karen Magno Silva, Cassio P Silva, Josué M Gonçalves, Frank H Quina

Abstract read
In one paragraph

Article in ACS omega, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it
0cells of the map it votes in
3citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed.

  1. Article
  2. Review
  3. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

5 authors.

Gustavo Thalmer M SilvaInstituto de Química, Universidade de São Paulo, Av. Lineu Prestes 748, Cidade Universitária, São Paulo 05508-000, Brazil.
Karen Magno SilvaInstituto de Química, Universidade de São Paulo, Av. Lineu Prestes 748, Cidade Universitária, São Paulo 05508-000, Brazil.
Cassio P SilvaInstituto de Química, Universidade de São Paulo, Av. Lineu Prestes 748, Cidade Universitária, São Paulo 05508-000, Brazil.
Josué M GonçalvesInstituto de Química, Universidade de São Paulo, Av. Lineu Prestes 748, Cidade Universitária, São Paulo 05508-000, Brazil.
Frank H QuinaInstituto de Química, Universidade de São Paulo, Av. Lineu Prestes 748, Cidade Universitária, São Paulo 05508-000, Brazil.

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Flavylium cations are synthetic analogues of anthocyanins, the natural plant pigments that are responsible for the majority of the red, blue, and purple colors of flowers, fruits, and leaves. Unlike anthocyanins, the properties and reactivity of flavylium cations can be manipulated by the nature and position of substituents on the flavylium cation chromophore. Currently, the most promising strategies for stabilizing the color of anthocyanins and flavylium cations appear to be to intercalate and/or adsorb them on solid surfaces and/or in confined spaces. We report here that hybrid pigments with improved thermal stability, fluorescence, and attractive colors are produced by the cation-exchange-mediated adsorption of flavylium cations (FL) on two synthetic clays, the mica-montmorillonite SYn-1, and the laponite SYnL-1. Compared to the FL/SYn-1 hybrid pigments, the FL/SYnL-1 pigments exhibited improved thermal stability as judged by color retention, better preferential adsorption of the cationic form of FL1 at neutral to mildly basic pH (pH 7-8), and lower susceptibility to color changes at pH 10. Although both clays adsorb the cationic form on their external surfaces, SYnL-1 gave more evidence of adsorption in the interlayer regions of the clay. This interlayer adsorption appears to be the contributing factor to the better properties of the FL/SYnL-1 hybrid pigments, pointing to this clay to be a promising inorganic matrix for the development of brightly colored, thermally more stable hybrid pigments based on cationic analogues of natural plant pigments.

Identifiers

PMID33110987
PMCPMC7581255

What OpenQuestion holds

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.