ArticleNature communications2020
Synergistic photoredox and copper catalysis by diode-like coordination polymer with twisted and polar copper-dye conjugation.
Article in Nature communications, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
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Who cites it
4 citing papers in PubMed.
- Confinement Effect in Metal-Organic Framework CuACS omega · 2024Article
- Metal-organic framework boosts heterogeneous electron donor-acceptor catalysis.Nature communications · 2023Article
- Active and stable alcohol dehydrogenase-assembled hydrogels via synergistic bridging of triazoles and metal ions.Nature communications · 2023Article
- Chemo- and regioselective benzylic C(spiScience · 2022Article
Corrections and comments
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Authors and funding
6 authors.
Funding
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Abstract
Synergistic photoredox and copper catalysis confers new synthetic possibilities in the pharmaceutical field, but is seriously affected by the consumptive fluorescence quenching of Cu(II). By decorating bulky auxiliaries into a photoreductive triphenylamine-based ligand to twist the conjugation between the triphenylamine-based ligand and the polar Cu(II)-carboxylate node in the coordination polymer, we report a heterogeneous approach to directly confront this inherent problem. The twisted and polar Cu(II)-dye conjunction endows the coordination polymer with diode-like photoelectronic behaviours, which hampers the inter- and intramolecular photoinduced electron transfer from the triphenylamine-moiety to the Cu(II) site and permits reversed-directional ground-state electronic conductivity, rectifying the productive loop circuit for synergising photoredox and copper catalysis in pharmaceutically valuable decarboxylative C(sp
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