ArticleNanomaterials (Basel, Switzerland)2020
Synthesis, Electrocatalytic and Gas Transport Characteristics of Pentagonally Structured Star-Shaped Nanocrystallites of Pd-Ag.
Article in Nanomaterials (Basel, Switzerland), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
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6 citing papers in PubMed, 25 citations in OpenAlex.
- Hydrogen Permeability of Composite Pd-Au/Pd-Cu Membranes and Methods for Their Preparation.Membranes · 2023Article
- Synthesis and Study of Palladium Mono- and Bimetallic (with Ag and Pt) Nanoparticles in Catalytic and Membrane Hydrogen Processes.Nanomaterials (Basel, Switzerland) · 2022Article
- Clean Electrochemical Synthesis of Pd-Pt Bimetallic Dendrites with High Electrocatalytic Performance for the Oxidation of Formic Acid.Materials (Basel, Switzerland) · 2022Article
- Reduction of Deuterium Level Supports Resistance of Neurons to Glucose Deprivation and Hypoxia: Study in Cultures of Neurons and on Animals.Molecules (Basel, Switzerland) · 2021Article
- Gas-Transport Characteristics of PdCu-Nb-PdCu Membranes Modified with Nanostructured Palladium Coating.International journal of molecular sciences · 2021Article
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5 authors at 2 institutions in 1 country.
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Abstract
The method of synthesis of bimetallic Pd-Ag pentagonally structured catalyst "nanostar" on the surface of Pd-23%Ag alloy films has been developed. The resulting catalyst was studied as a highly active functional layer for methanol oxidation reaction (MOR) in alkaline media and the intensification of hydrogen transport through the Pd-23%Ag membrane in the processes of hydrogen diffusion purification. A modifying layer with a controlled size, composition and excellent electrocatalytic activity was synthesized by electrochemical deposition at a reduced current density compared to classical methods. The low deposition rate affects the formation of pentagonally structured nanocrystallites, allowing Pd and Ag particles to form well-defined structures due to the properties of the surfactant used. Electrochemical studies have demonstrated that the catalyst synthesized by the "nanostar" method shows better electrocatalytic activity in relation to MOR and demonstrates a higher peak current (up to 17.82 µA cm
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