Non-Absorbing Dielectric Materials for Surface-Enhanced Spectroscopies and Chiral Sensing in the UV.

Low-loss dielectric nanomaterials are being extensively studied as novel platforms for enhanced light-matter interactions. Dielectric materials are more versatile than metals when nanostructured as they are able to generate simultaneously electric- and magnetic-type resonances. This unique property gives rise to a wide gamut of new phenomena not observed in metal nanostructures such as directional scattering conditions or enhanced optical chirality density. Traditionally studied dielectrics such as Si, Ge or GaP have an operating range constrained to the infrared and/or the visible range. Tuning their resonances up to the UV, where many biological samples of interest exhibit their absorption bands, is not possible due to their increased optical losses via heat generation. Herein, we report a quantitative survey on the UV optical performance of 20 different dielectric nanostructured materials for UV surface light-matter interaction based applications. The near-field intensity and optical chirality density averaged over the surface of the nanoparticles together with the heat generation are studied as figures of merit for this comparative analysis.