Evidence map›Paper›PMID 33090703›Full record

ArticleChemSusChem2020

Nickel is a Different Pickle: Trends in Water Oxidation Catalysis for Molecular Nickel Complexes.

Joeri Hessels, Eduard Masferrer-Rius, Fengshou Yu, Remko J Detz, Robertus J M Klein Gebbink, Joost N H Reek

Open access · hybridAbstract read
In one paragraph

Article in ChemSusChem, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.

0numbers the graph read from it
0cells of the map it votes in
6citing papers in PubMed
0.7field-weighted citation impact, top 33% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

6 citing papers in PubMed, 31 citations in OpenAlex.

  1. Article
  2. A Polymer-Derived Co(Fe)OACS catalysis · 2023
    Article
  3. Article
  4. Review
  5. Review
  6. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors at 3 institutions in 2 countries.

Joeri HesselsHomogeneous, Supramolecular and Bio-Inspired Catalysis, Van 't Hoff Institute for Molecular Sciences, University of Amsterdam, Science Park 904, 1098 XH, Amsterdam, The Netherlands.
Eduard Masferrer-RiusOrganic Chemistry & Catalysis, Debye Institute for Nanomaterials Science, Utrecht University, Universiteitsweg 99, 3584 CG, Utrecht, The Netherlands.
Fengshou YuHomogeneous, Supramolecular and Bio-Inspired Catalysis, Van 't Hoff Institute for Molecular Sciences, University of Amsterdam, Science Park 904, 1098 XH, Amsterdam, The Netherlands.
Remko J DetzCurrent address: TNO Energy Transition, Energy Transition Studies, Radarweg 60, 1043 NT, Amsterdam, The Netherlands.
Robertus J M Klein GebbinkOrganic Chemistry & Catalysis, Debye Institute for Nanomaterials Science, Utrecht University, Universiteitsweg 99, 3584 CG, Utrecht, The Netherlands.
Joost N H ReekHomogeneous, Supramolecular and Bio-Inspired Catalysis, Van 't Hoff Institute for Molecular Sciences, University of Amsterdam, Science Park 904, 1098 XH, Amsterdam, The Netherlands.ORCID http://orcid.org/0000-0001-5024-508X
Institute for Atomic and Molecular Physics · NLUtrecht University · NLEnergy Research Centre of the Netherlands · NL

Funding

Foundation for Fundamental Research on Matter (FOM)Netherlands Organisation for Scientific Research (NWO)
6 · The paper itself

Abstract

The development of novel water oxidation catalysts is important in the context of renewable fuels production. Ligand design is one of the key tools to improve the activity and stability of molecular catalysts. The establishment of ligand design rules can facilitate the development of improved molecular catalysts. In this paper it is shown that chemical oxidants can be used to probe oxygen evolution activity for nickel-based systems, and trends are reported that can improve future ligand design. Interestingly, different ligand effects were observed in comparison to other first-row transition metal complexes. For example, nickel complexes with secondary amine donors were more active than with tertiary amine donors, which is the opposite for iron complexes. The incorporation of imine donor groups in a cyclam ligand resulted in the fastest and most durable nickel catalyst of our series, achieving oxygen evolution turnover numbers up to 380 and turnover frequencies up to 68 min

Indexed as

homogeneous catalysisnickelstructure-activity relationshipswater oxidationwater splitting

Identifiers

PMID33090703
PMCPMC7756549
OpenAlexW3093606406

What OpenQuestion holds

Textmetadata
LicenceCC BY-NC
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.