Evidence map›Paper›PMID 33047818›Full record

ArticleChemistry (Weinheim an der Bergstrasse, Germany)2021

Interface Amorphization of Two-Dimensional Black Phosphorus upon Treatment with Diazonium Salts.

Aleksandra Mitrović, Stefan Wild, Vicent Lloret, Michael Fickert, Mhamed Assebban, Bence G Márkus, Ferenc Simon, Frank Hauke, Gonzalo Abellán, Andreas Hirsch

Open access · hybridAbstract read
In one paragraph

Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.

0numbers the graph read from it
0cells of the map it votes in
7citing papers in PubMed
1.2field-weighted citation impact, top 23% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

7 citing papers in PubMed, 23 citations in OpenAlex.

  1. Article
  2. Review
  3. Ultra-Narrow Phosphorene Nanoribbons Produced by Facile Electrochemical Process.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2022
    Article
  4. Article
  5. Interlayer Coordination of Pd-Pd Units in Exfoliated Black Phosphorus.Journal of the American Chemical Society · 2021
    Article
  6. Article
  7. Review
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

10 authors at 3 institutions in 4 countries.

Aleksandra MitrovićChair of Organic Chemistry II and Joint Institute of Advanced Materials, and Processes (ZMP), Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), Nikolaus Fiebiger-Strasse 10, 91058, Dr.-Mack Strasse 81, 90762, Erlangen and Fürth, Germany.
Stefan WildChair of Organic Chemistry II and Joint Institute of Advanced Materials, and Processes (ZMP), Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), Nikolaus Fiebiger-Strasse 10, 91058, Dr.-Mack Strasse 81, 90762, Erlangen and Fürth, Germany.
Vicent LloretChair of Organic Chemistry II and Joint Institute of Advanced Materials, and Processes (ZMP), Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), Nikolaus Fiebiger-Strasse 10, 91058, Dr.-Mack Strasse 81, 90762, Erlangen and Fürth, Germany.
Michael FickertChair of Organic Chemistry II and Joint Institute of Advanced Materials, and Processes (ZMP), Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), Nikolaus Fiebiger-Strasse 10, 91058, Dr.-Mack Strasse 81, 90762, Erlangen and Fürth, Germany.
Mhamed AssebbanChair of Organic Chemistry II and Joint Institute of Advanced Materials, and Processes (ZMP), Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), Nikolaus Fiebiger-Strasse 10, 91058, Dr.-Mack Strasse 81, 90762, Erlangen and Fürth, Germany.
Bence G MárkusDepartment of Physics, Budapest University of Technology, and Economics and MTA-BME, Lendület Spintronics Research Group, (PROSPIN), PO Box 91, 1521, Budapest, Hungary.ORCID http://orcid.org/0000-0003-1472-0482
Ferenc SimonDepartment of Physics, Budapest University of Technology, and Economics and MTA-BME, Lendület Spintronics Research Group, (PROSPIN), PO Box 91, 1521, Budapest, Hungary.
Frank HaukeChair of Organic Chemistry II and Joint Institute of Advanced Materials, and Processes (ZMP), Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), Nikolaus Fiebiger-Strasse 10, 91058, Dr.-Mack Strasse 81, 90762, Erlangen and Fürth, Germany.
Gonzalo AbellánChair of Organic Chemistry II and Joint Institute of Advanced Materials, and Processes (ZMP), Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), Nikolaus Fiebiger-Strasse 10, 91058, Dr.-Mack Strasse 81, 90762, Erlangen and Fürth, Germany.ORCID http://orcid.org/0000-0003-1564-6210
Andreas HirschChair of Organic Chemistry II and Joint Institute of Advanced Materials, and Processes (ZMP), Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), Nikolaus Fiebiger-Strasse 10, 91058, Dr.-Mack Strasse 81, 90762, Erlangen and Fürth, Germany.
Friedrich-Alexander-Universität Erlangen-Nürnberg · DEBudapest University of Technology and Economics · HUUniversitat de València · ES

Funding

Alexander von Humboldt-Stiftung postdoctoral fellowshipDeutsche Forschungsgemeinschaft Cluster of "Excellence Engineering of Advanced Materials"Deutsche Forschungsgemeinschaft FLAG-ERA AB694/2-1Deutsche Forschungsgemeinschaft SFB 953 "Synthetic Carbon Allotropes"Dirección General de Investigación Científica y Técnica Excellence Unit María de Maeztu (CEX2019-000919-M)Dirección General de Universidades e Investigación PID2019-111742GA-I00European Commission 604391 Graphene FlagshipGeneralitat Valenciana CIDEGENT/2018/001Generalitat Valenciana iDiFEDER/2018/061 co-financed by FEDERHorizon 2020 ERC Advanced Grant 742145 B-PhosphoChemHorizon 2020 Framework Programme ERC Starting Grant 2D-PnictoChem 804110National Research, Development, and Innovation Office of Hungary (NKFIH) Grant Nrs. K119442 and 2017-1.2.1-NKP-2017-00001
6 · The paper itself

Abstract

Two-dimensional (2D) black phosphorus (BP) represents one of the most appealing 2D materials due to its electronic, optical, and chemical properties. Many strategies have been pursued to face its environmental instability, covalent functionalization being one of the most promising. However, the extremely low functionalization degrees and the limitations in proving the nature of the covalent functionalization still represent challenges in many of these sheet architectures reported to date. Here we shine light on the structural evolution of 2D-BP upon the addition of electrophilic diazonium salts. We demonstrated the absence of covalent functionalization in both the neutral and the reductive routes, observing in the latter case an unexpected interface conversion of BP to red phosphorus (RP), as characterized by Raman,

Indexed as

amorphizationBalz-Schiemann productblack phosphorusred phosphorussacrificial catalysts

Identifiers

PMID33047818
PMCPMC7898634
OpenAlexW3092289418

What OpenQuestion holds

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LicenceCC BY-NC-ND
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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.