ArticlePolymers2020
Novel Copper Photoredox Catalysts for Polymerization: An In Situ Synthesis of Metal Nanoparticles.
Article in Polymers, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
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Who cites it
6 citing papers in PubMed.
- Light-enhanced catalytic activity of stable and large gold nanoparticles in homocoupling reactions.Scientific reports · 2024Article
- Photochemical Synthesis of Noble Metal Nanoparticles: Influence of Metal Salt Concentration on Size and Distribution.International journal of molecular sciences · 2023Article
- Article
- Article
- Light-Assisted Synthesis of Silver and Gold Nanoparticles by New Benzophenone Derivatives.ACS omega · 2023Article
- Efficacy Analysis of In Situ Synthesis of Nanogold via Copper/Iodonium/Amine/Gold System under a Visible Light.Polymers · 2021Article
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Authors and funding
6 authors.
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Abstract
The copper II complex (HLCuCl) carrying 2,4 dinitrophenylhydrazone (L) is synthesized and evaluated as a new photoredox catalyst/photoinitiator in combination with triethylamine (TEA) and iodonium salt (Iod) for the radical polymerization of ethylene glycol diacrylate during exposure to visible light using a photoreactor at 419 nm. The copper complex reactivity with TEA/Iod salt/gold chloride showed a good production and stability of gold nanoparticles. Finally, the high performance of Cu (II) complex for radical photopolymerization incorporating gold nanoparticles is provided. The photochemical mechanisms for the production of initiating radicals are studied using cyclic voltammetry. Polymer nanocomposites containing gold nanoparticles (Au NPs) in situ photogenerated during the irradiation process were prepared. The formation of Au NPs inside the polymer matrix was through UV-Vis and EDS/SEM analyses.
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