Evidence map›Paper›PMID 33016072›Full record

ReviewJournal of the American Chemical Society2020

Structurally Modified Norbornenes: A Key Factor to Modulate Reaction Selectivity in the Palladium/Norbornene Cooperative Catalysis.

Renhe Li, Guangbin Dong

Abstract readReview
In one paragraph

Review in Journal of the American Chemical Society, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 29 papers.

0numbers the graph read from it
0cells of the map it votes in
29citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

29 citing papers in PubMed.

  1. Article
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  9. Ligand-Controlled NondirectedACS catalysis · 2024
    Article
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  14. Article
  15. Article
  16. Article
  17. Review
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  19. Article
  20. RhodiumChemical science · 2022
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

2 authors.

Renhe LiDepartment of Chemistry, University of Chicago, Chicago, Illinois 60637, United States.
Guangbin DongDepartment of Chemistry, University of Chicago, Chicago, Illinois 60637, United States.ORCID 0000-0003-1331-6015

Funding

New Directions in Palladium/Norbornene Cooperative-RenewalR01GM124414 · NIGMS · UNIVERSITY OF CHICAGO · PI DONG, GUANGBIN · 2018 to 2025
$2.6M
NIGMS NIH HHS R01 GM124414
6 · The paper itself

Abstract

Palladium/norbornene (Pd/NBE) cooperative catalysis has received enormous attention and found numerous synthetic applications in the past two decades. Considering the critical roles that NBE plays in the catalytic cycle, the use of structurally modified NBEs (smNBEs), starting from 2015, has become an important approach to address limitations and modulate reaction selectivity in Pd/NBE catalysis. This Perspective highlights the development of three types of smNBEs: C1-substituted, C2-substituted, and C5-substituted or C5,C6-disubstituted NBEs, as well as their synthetic applications toward site-selective C-H functionalization. A focus is on the structure-activity relationship of smNBEs in these reactions, and rationales for using smNBEs in many cases have also been provided.

Indexed as

CatalysisMolecular StructureNorbornanesOrganometallic CompoundsPalladiumStructure-Activity RelationshipNorbornanesOrganometallic CompoundsPalladium

Identifiers

PMID33016072
PMCPMC8011229

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.