Evidence map›Paper›PMID 33001067›Full record

ArticleChemical communications (Cambridge, England)2020

Hydrogenation and electrocatalytic reduction of carbon dioxide to formate with a single Co catalyst.

Fang Wang, Austin T Cannon, Moumita Bhattacharya, Robert Baumgarten, Ryan T VanderLinden, Caroline T Saouma

Abstract read
In one paragraph

Article in Chemical communications (Cambridge, England), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Electrocatalytic COChemical science · 2024
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors.

Fang WangDepartment of Chemistry, University of Utah, 315 S. 1400 E., Salt Lake City, UT 84112, USA. caroline.saouma@utah.edu.ORCID http://orcid.org/0000-0002-3601-6210
Austin T CannonDepartment of Chemistry, University of Utah, 315 S. 1400 E., Salt Lake City, UT 84112, USA. caroline.saouma@utah.edu.ORCID http://orcid.org/0000-0002-7753-5236
Moumita BhattacharyaDepartment of Chemistry, University of Utah, 315 S. 1400 E., Salt Lake City, UT 84112, USA. caroline.saouma@utah.edu.ORCID http://orcid.org/0000-0003-1189-6685
Robert BaumgartenDepartment of Chemistry, University of Utah, 315 S. 1400 E., Salt Lake City, UT 84112, USA. caroline.saouma@utah.edu.
Ryan T VanderLindenDepartment of Chemistry, University of Utah, 315 S. 1400 E., Salt Lake City, UT 84112, USA. caroline.saouma@utah.edu.ORCID http://orcid.org/0000-0002-0128-1284
Caroline T SaoumaDepartment of Chemistry, University of Utah, 315 S. 1400 E., Salt Lake City, UT 84112, USA. caroline.saouma@utah.edu.ORCID http://orcid.org/0000-0003-1170-6175

Funding

Pd-Catalyzed Olefin Functionalization Reactions for Organic SynthesisR01GM063540 · NIGMS · UNIVERSITY OF UTAH · PI SIGMAN, MATTHEW S · 2002 to 2019
$5.3M
EXTRAMURAL RESEARCH FACILITIES CONSTRUCTIONC06RR017539 · NCRR · UNIVERSITY OF UTAH · PI PUGMIRE, RONALD J · 2003 to 2003
$3.8M
A 500MHz NMR Spectrometer with AutomationS10OD025241 · OD · UNIVERSITY OF UTAH · PI FLYNN, PETER F · 2018 to 2018
$600k
NCRR NIH HHS C06 RR017539NIGMS NIH HHS R01 GM063540NIH HHS S10 OD025241
6 · The paper itself

Abstract

A cobalt(i) complex is shown to be capable of both electrocatalytic reduction and hydrogenation of CO2 to formate. Several proposed intermediates are characterized and thus form the basis for a proposed mechanism that allows for the dual reactivity: reduction of CO2via H2 addition, and H+/e- equivalents. The work makes use of a novel tris(phosphino) ligand. When a pendent amine is attached to the ligand, no change in catalytic reactivity is observed.

Identifiers

PMID33001067
PMCPMC7703687

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.