ArticleChemistry (Weinheim an der Bergstrasse, Germany)2020
Synthetically Versatile Nitrogen Acyclic Carbene Stabilized Gold Nanoparticles.
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.
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Who cites it
7 citing papers in PubMed.
- Seed-mediated synthesis of NHC-stabilised Cu@Au core-shell nanoparticles from an NHC-Au(I) complex.Nanoscale · 2026Article
- Water-soluble N-heterocyclic carbene stabilized gold nanoparticles by top-down synthesis: performance in catalysis and photoacoustic imaging.Nanoscale · 2025Article
- Bidentate Acyclic Diamino Carbene-Stabilized Gold Nanoparticles from Symmetric and Asymmetric Gold(I) Complexes: Synthesis, Characterization, and Catalytic Activity.Inorganic chemistry · 2025Article
- Gold Acyclic Diaminocarbene Complexes as Selective and Potent Agents for Multitarget Cancer Therapy.Inorganic chemistry · 2025Article
- Reactivity of Diamines in Acyclic Diamino Carbene Gold Complexes.Inorganic chemistry · 2022Article
- Catalytically Active Gold Nanomaterials Stabilized by N-heterocyclic Carbenes.Chemistry, an Asian journal · 2021Review
- Synthetically Versatile Nitrogen Acyclic Carbene Stabilized Gold Nanoparticles.Chemistry (Weinheim an der Bergstrasse, Germany) · 2020Article
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Authors and funding
4 authors.
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Abstract
N-heterocyclic carbenes (NHCs) have received significant attention as gold nanoparticle stabilizers due to their strong binding affinity towards gold. However, their tunability is limited by the difficulty in obtaining nonsymmetric NHCs. In this regard, N-acyclic carbenes (NACs) are attractive alternatives due to their high synthetic versatility, allowing easy tuning of their steric and electronic properties towards specific applications. This work reports the first series of stable and monodisperse NAC-functionalized gold nanoparticles. These particles with sizes ranging 3.8 to 11.6 nm were characterized using NMR, UV/Vis and TEM. The nanoparticles display good stability at elevated temperatures and for extended periods both dried or dispersed in a medium, as well as in the presence of exogenous thiols. Importantly, these NAC-stabilized gold nanoparticles offer a promising and versatile alternative to NHC-stabilized gold nanoparticles.
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