ArticleAccounts of chemical research2020
Light-Activated Olefin Metathesis: Catalyst Development, Synthesis, and Applications.
Article in Accounts of chemical research, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 16 papers.
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Who cites it
16 citing papers in PubMed, 64 citations in OpenAlex.
- Photoswitchable latent monomers enable on‑demand metathesis.Nature chemistry · 2026Article
- Photoswitchable olefins as latent metathesis monomers for controlled polymerization.Nature chemistry · 2026Article
- Low-energy photoredox catalysis.Nature reviews. Chemistry · 2025Review
- Preserving precise choreography of bonds in Z-stereoretentive olefin metathesis by using quinoxaline-2,3-dithiolate ligand.Nature communications · 2024Article
- Volumetric Additive Manufacturing of Dicyclopentadiene by Solid-State Photopolymerization.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
- Recent Applications of Photothermal Conversion in Organic Synthesis.ACS central science · 2024Review
- Latency for All: Enabling Latency of Hoveyda-Grubbs Second-Generation Catalysts by Adding Phosphite Ligands.Journal of the American Chemical Society · 2024Article
- Crystal structure of [1,3-bis-(2,4,6-tri-methyl-phen-yl)imidazolidin-2-yl-idene]di-chlorido-(2-{[(2-methoxyeth-yl)(meth-yl)amino]-meth-yl}benzyl-idene)ruth-en-ium.Acta crystallographica. Section E, Crystallographic communications · 2024Article
- Lighting up hot stuff.Nature chemistry · 2023Article
- Plasmonic visible-near infrared photothermal activation of olefin metathesis enabling photoresponsive materials.Nature chemistry · 2023Article
- Merging Grubbs second-generation catalyst with photocatalysis enablesChemical science · 2022Article
- Continuous Additive Manufacturing using Olefin Metathesis.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2022Article
- Recent Advances in the Domain of Cyclic (Alkyl)(Amino) Carbenes.Chemistry, an Asian journal · 2022Review
- Olefin Metathesis Catalyzed by a Hoveyda-Grubbs-like Complex Chelated to Bis(2-mercaptoimidazolyl) Methane: A Predictive DFT Study.The journal of physical chemistry. A · 2022Article
- Synthesis and Catalytic Properties of a Very Latent Selenium-Chelated Ruthenium Benzylidene Olefin Metathesis Catalyst.Organometallics · 2021Article
- Light-Driven gem Hydrogenation: An Orthogonal Entry into "Second-Generation" Ruthenium Carbene Catalysts for Olefin Metathesis.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
Corrections and comments
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Authors and funding
4 authors at 1 institution in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The most important means for tuning and improving a catalyst's properties is the delicate exchange of the ligand shell around the central metal atom. Perhaps for no other organometallic-catalyzed reaction is this statement more valid than for ruthenium-based olefin metathesis. Indeed, even the simple exchange of an oxygen atom for a sulfur atom in a chelated ruthenium benzylidene about a decade ago resulted in the development of extremely stable, photoactive catalysts. This Account presents our perspective on the development of dormant olefin metathesis catalysts that can be activated by external stimuli and, more specifically, the use of light as an attractive inducing agent.The insight gained from a deeper understanding of the properties of
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.