ArticleAngewandte Chemie (International ed. in English)2021
En Route Towards the Control of Luminescent, Optically-Active 3D Architectures.
Article in Angewandte Chemie (International ed. in English), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.
What it found
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The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
5 citing papers in PubMed.
- Transformation of the Phosphorus Atom in Hexacyclic Polyaromates and Its Impact on Physicochemical Properties.The Journal of organic chemistry · 2026Article
- Synthesis of Quinolizidine-Based 1,4-Azaphosphinines via Cyclization of Heteroarylmethyl(alkynyl)phosphinates.The Journal of organic chemistry · 2026Article
- Poly(p-phenylene phosphaborene): A Modified Poly(p-phenylene vinylene) with π-Conjugated B═P Linkages.Angewandte Chemie (International ed. in English) · 2025Article
- Synthesis, Post-Functionalization and Properties of Diphosphapentaarenes.Chemistry (Weinheim an der Bergstrasse, Germany) · 2023Article
- En Route Towards the Control of Luminescent, Optically-Active 3D Architectures.Angewandte Chemie (International ed. in English) · 2021Article
Corrections and comments
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Authors and funding
3 authors.
Funding
Abstract
π-Extended systems are key components for the development of future organic electronic technologies. While conceiving molecules with improved properties is fundamental for the evolution of materials science, keeping control over the 3D arrangement of molecules represents an ever-expanding challenge. Herein, a synthetic protocol to replace carbon atoms of π-systems by dissymmetric phosphorus atoms is reported; in particular, it allowed for conceiving new fused phosphapyrene derivatives with improved properties. The presence of dissymmetric phosphorus atoms precluded the formation of excimers. X-ray diffraction revealed that, meanwhile, strong intermolecular interactions are taking place in the solid state. The phosphapyrenes photoluminesce in the visible region with high quantum yields; importantly, they are CD-active. In addition, the unique non-planar features of phosphorus atoms allowed for the control of the 3D arrangement of molecules, rendering lemniscate-like structures. Based on our discoveries, we envisage the possibility to construct higher-order, chiral 3D architectures from larger phosphorus-containing π-systems.
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Registered trials
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