ArticleEnvironmental science & technology letters2020
Contribution of Particulate Nitrate Photolysis to Heterogeneous Sulfate Formation for Winter Haze in China.
Article in Environmental science & technology letters, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
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Who cites it
2 citing papers in PubMed.
- Wintertime Formation of Large Sulfate Particles in China and Implications for Human Health.Environmental science & technology · 2023Article
- Role of Dust and Iron Solubility in Sulfate Formation during the Long-Range Transport in East Asia Evidenced byEnvironmental science & technology · 2022Article
Corrections and comments
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Authors and funding
14 authors.
Funding
Abstract
Nitrate and sulfate are two key components of airborne particulate matter (PM). While multiple formation mechanisms have been proposed for sulfate, current air quality models commonly underestimate its concentrations and mass fractions during northern China winter haze events. On the other hand, current models usually overestimate the mass fractions of nitrate. Very recently, laboratory studies have proposed that nitrous acid (N(III)) produced by particulate nitrate photolysis can oxidize sulfur dioxide to produce sulfate. Here, for the first time, we parameterize this heterogeneous mechanism into the state-of-the-art Community Multi-scale Air Quality (CMAQ) model and quantify its contributions to sulfate formation. We find that the significance of this mechanism mainly depends on the enhancement effects (by 1-3 orders of magnitude as suggested by the available experimental studies) of nitrate photolysis rate constant (
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Registered trials
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