ArticleChemistry of materials : a publication of the American Chemical Society2020
Crystal Orientation Dependent Oxidation Modes at the Buried Graphene-Cu Interface.
Article in Chemistry of materials : a publication of the American Chemical Society, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
What it found
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Who cites it
6 citing papers in PubMed, 29 citations in OpenAlex.
- Time of flight secondary ion mass spectrometry imaging of contaminant species in chemical vapour deposited graphene on copper.Beilstein journal of nanotechnology · 2026Article
- Fast crystallographic texture mapping of atomically thin hBN films on Ni(111) using secondary electron contrast.Nanoscale advances · 2025Article
- A Polycrystalline Pd Surface Studied by Two-Dimensional Surface Optical Reflectance during CO Oxidation: Bridging the Materials Gap.ACS applied materials & interfaces · 2024Article
- Article
- Effect of Functionalization of Reduced Graphene Oxide Coatings with Nitrogen and Sulfur Groups on Their Anti-Corrosion Properties.Materials (Basel, Switzerland) · 2021Article
- Chemical Vapour Deposition of Graphene for Durable Anticorrosive Coating on Copper.Nanomaterials (Basel, Switzerland) · 2020Article
Corrections and comments
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Authors and funding
7 authors at 3 institutions in 2 countries.
Funding
No grant is acknowledged in the PubMed record.
Abstract
We combine spatially resolved scanning photoelectron spectroscopy with confocal Raman and optical microscopy to reveal how the oxidation of the buried graphene-Cu interface relates to the Cu crystallographic orientation. We analyze over 100 different graphene covered Cu (high and low index) orientations exposed to air for 2 years. Four general oxidation modes are observed that can be mapped as regions onto the polar plot of Cu surface orientations. These modes are (1) complete, (2) irregular, (3) inhibited, and (4) enhanced wrinkle interface oxidation. We present a comprehensive characterization of these modes, consider the underlying mechanisms, compare air and water mediated oxidation, and discuss this in the context of the diverse prior literature in this area. This understanding incorporates effects from across the wide parameter space of 2D material interface engineering, relevant to key challenges in their emerging applications, ranging from scalable transfer to electronic contacts, encapsulation, and corrosion protection.
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Registered trials
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