ArticleChemistry (Weinheim an der Bergstrasse, Germany)2020
Synthesis of Low-Valent Dinuclear Group 14 Compounds with Element-Element Bonds by Transylidation.
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.
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Who cites it
7 citing papers in PubMed.
- Synthesis and Isolation of Bismuth Scorpionate Complexes: Toward Bond Activation via Bismuth-Ligand Cooperation.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Probing the donor strength of yldiide ligands: synthesis, structure and reactivity of rhodium complexes with a PCChemical science · 2023Article
- Ylide-Stabilized Phosphenium Cations: Impact of the Substitution Pattern on the Coordination Chemistry.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Accessing Cationic α-Silylated and α-Germylated Phosphorus Ylides.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Single-Site and Cooperative Bond Activation Reactions with Ylide-Functionalized Tetrylenes: A Computational Study.European journal of inorganic chemistry · 2021Article
- Synthesis, Crystal and Electronic Structures of a Thiophosphinoyl- and Amino-Substituted Metallated Ylide.ChemistryOpen · 2021Article
- Synthesis of Low-Valent Dinuclear Group 14 Compounds with Element-Element Bonds by Transylidation.Chemistry (Weinheim an der Bergstrasse, Germany) · 2020Article
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Authors and funding
6 authors.
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Abstract
Dinuclear low-valent compounds of the heavy main group elements are rare species owing to their intrinsic reactivity. However, they represent desirable target molecules due to their unusual bonding situations as well as applications in bond activations and materials synthesis. The isolation of such compounds usually requires the use of substituents that provide sufficient stability and synthetic access. Herein, we report on the use of strongly donating ylide-substituents to access low-valent dinuclear group 14 compounds. The ylides not only impart steric and electronic stabilization, but also allow facile synthesis via transfer of an ylide from tetrylene precursors of type
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