ArticleNature communications2020
Organic-to-inorganic structural chirality transfer in a 2D hybrid perovskite and impact on Rashba-Dresselhaus spin-orbit coupling.
Article in Nature communications, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 76 papers.
What it found
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Who cites it
76 citing papers in PubMed, 415 citations in OpenAlex.
- Hidden spin-valley locking stabilizes nanosecond spin polarization in 2D perovskites.Nature nanotechnology · 2026Article
- Tracing the Origin of Chiropticity in Lead-Halide Perovskite Nanomaterials.ACS physical chemistry Au · 2026Review
- Chirality-induced magnetoresistance in hybrid organic-inorganic perovskite semiconductors.Science advances · 2026Article
- Coupled Molecular and Framework Descriptors for Band-Edge Spin Splitting in Chiral Hybrid Organic-Inorganic Perovskites.Journal of the American Chemical Society · 2026Article
- High-performance near-infrared circularly polarized electroluminescence with an emission peak beyond 900 nm.Nature communications · 2026Article
- Chiral Metal Halides toward Circularly Polarized Photodetectors.Advanced materials (Deerfield Beach, Fla.) · 2026Review
- Ionic gel-mediated synthesis of nanostructured chiral 2D halide perovskites with amplified chiroptical response.Nature communications · 2026Article
- Chirality Transfer to the Magnetic Sublattice in the Hybrid Perovskite (R)-/(S)-3-Fluoropyrrolidinium Copper(II) Chloride.Journal of the American Chemical Society · 2026Article
- Excitonic Structure and Dynamics in Two-Dimensional Halide Perovskites.Nano letters · 2026Article
- Organic Cation Conformation-Modulated Dimensionality in Chiral Metal Halides for Enhancing Linear and Nonlinear Chiroptical Properties.Angewandte Chemie (International ed. in English) · 2026Article
- Tracking Chirality Evolution in Tellurium Nanocrystals Via Polarization-Resolved Second-Harmonic Scattering.Nano letters · 2026Article
- Optical access of spin-polarized excited states in Cs(PbMgZnCd)BrNature communications · 2026Article
- Article
- Chiral manganese halide isomers: decoding the spatial stacking effect on second-harmonic generation circular dichroism.Chemical science · 2026Article
- Organic-Inorganic Metal Halide Perovskites: Toward Stability, Chirality, and AI-Guided Discovery.ACS central science · 2026Review
- Spin Injection and Emission Helicity Switching in a 2D Perovskite/WSeNano letters · 2026Article
- Chiral Metal Halide Perovskites for Spin-Polarized Light-Emitting Diodes.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- Chirality transfer from chiral perovskite to molecular dopants via charge transfer states.Nature communications · 2026Article
- Precision engineering chiral interfaces for efficient spin injection in metal halide heterostructures.Nature communications · 2026Article
- Polarized luminescence in halide perovskite nanocrystals: from fundamental microscopic mechanisms to advanced optoelectronic applications.Frontiers in chemistry · 2026Review
16 more citing papers are in PubMed but not listed here.
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
10 authors at 2 institutions in 1 country.
Funding
Abstract
Translation of chirality and asymmetry across structural motifs and length scales plays a fundamental role in nature, enabling unique functionalities in contexts ranging from biological systems to synthetic materials. Here, we introduce a structural chirality transfer across the organic-inorganic interface in two-dimensional hybrid perovskites using appropriate chiral organic cations. The preferred molecular configuration of the chiral spacer cations, R-(+)- or S-(-)-1-(1-naphthyl)ethylammonium and their asymmetric hydrogen-bonding interactions with lead bromide-based layers cause symmetry-breaking helical distortions in the inorganic layers, otherwise absent when employing a racemic mixture of organic spacers. First-principles modeling predicts a substantial bulk Rashba-Dresselhaus spin-splitting in the inorganic-derived conduction band with opposite spin textures between R- and S-hybrids due to the broken inversion symmetry and strong spin-orbit coupling. The ability to break symmetry using chirality transfer from one structural unit to another provides a synthetic design paradigm for emergent properties, including Rashba-Dresselhaus spin-polarization for hybrid perovskite spintronics and related applications.
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What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.