ArticleAngewandte Chemie (International ed. in English)2020
A Unified Strategy for Arylsulfur(VI) Fluorides from Aryl Halides: Access to Ar-SOF
Article in Angewandte Chemie (International ed. in English), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 18 papers.
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Who cites it
18 citing papers in PubMed.
- Regioselective synthesis of aza-saccharinsChemical science · 2026Article
- Bench-stable reagents for modular access to persulfuranyl scaffolds.Nature communications · 2025Article
- Advances in sulfonyl exchange chemical biology: expanding druggable target space.Chemical science · 2025Review
- Electrochemical Conversions of Sulfenamides into Sulfonimidoyl- and Sulfondiimidoyl Fluorides.JACS Au · 2025Article
- Overcoming a Radical Polarity Mismatch in Strain-Release Pentafluorosulfanylation of [1.1.0]Bicyclobutanes: An Entryway to Sulfone- and Carbonyl-Containing SFAngewandte Chemie (International ed. in English) · 2024Article
- Photoredox-catalyzed stereo- and regioselective vicinal fluorosulfonyl-borylation of unsaturated hydrocarbons.Chemical science · 2023Article
- Fluoroalkylated hypervalent sulfur fluorides: radical addition of arylchlorotetrafluoro-λChemical science · 2023Article
- Advances in the construction of diverse SuFEx linkers.National science review · 2023Review
- Strain-Release Pentafluorosulfanylation and Tetrafluoro(aryl)sulfanylation of [1.1.1]Propellane: Reactivity and Structural Insight.Angewandte Chemie (International ed. in English) · 2022Article
- Oxidative Fluorination of Heteroatoms Enabled by Trichloroisocyanuric Acid and Potassium Fluoride.Angewandte Chemie (International ed. in English) · 2022Review
- A practical fluorosulfonylating platform via photocatalytic imidazolium-based SONature communications · 2022Article
- (Hetero)aryl-SAngewandte Chemie (International ed. in English) · 2022Review
- Functional group divergence and the structural basis of acridine photocatalysis revealed by direct decarboxysulfonylation.Chemical science · 2022Article
- Radical 1-Fluorosulfonyl-2-alkynylation of Unactivated Alkenes.Angewandte Chemie (International ed. in English) · 2022Article
- Redox-Neutral Organometallic Elementary Steps at Bismuth: Catalytic Synthesis of Aryl Sulfonyl Fluorides.Journal of the American Chemical Society · 2021Article
- Synthesis and Physicochemical Properties of 2-SFACS organic & inorganic Au · 2021Article
- The Emerging Applications of Sulfur(VI) Fluorides in Catalysis.ACS catalysis · 2021Review
- A Unified Strategy for Arylsulfur(VI) Fluorides from Aryl Halides: Access to Ar-SOFAngewandte Chemie (International ed. in English) · 2020Article
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2 authors.
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Abstract
A convenient protocol to selectively access various arylsulfur(VI) fluorides from commercially available aryl halides in a divergent fashion is presented. Firstly, a novel sulfenylation reaction with the electrophilic N-(chlorothio)phthalimide (Cl-S-Phth) and arylzinc reagents afforded the corresponding Ar-S-Phth compounds. Subsequently, the S(II) atom was selectively oxidized to distinct fluorinated sulfur(VI) compounds under mild conditions. Slight modifications on the oxidation protocol permit the chemoselective installation of 1, 3, or 4 fluorine atoms at the S(VI) center, affording the corresponding Ar-SO
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