ArticleNature communications2020
Cage-confined photocatalysis for wide-scope unusually selective [2 + 2] cycloaddition through visible-light triplet sensitization.
Article in Nature communications, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 22 papers.
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The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
22 citing papers in PubMed.
- Oxidative PCET-Triggered Benzylic C─H Iminolactonization via 1,5-HAT/Cyclization Enabled by Cage-Confined Photocatalysis.Angewandte Chemie (International ed. in English) · 2026Article
- From Monomers to Aggregates: The Influence of Redox State and Structure on the First Excited States of Eumelanin and Pheomelanin.International journal of molecular sciences · 2026Article
- Selective photocatalytic oxidative cleavage of terminal alkynes to carboxylic acids within a water-soluble PdChemical science · 2026Article
- Kaemphenolide: a cyclobutane-bearing phenylpropanoid from Kaempferia galanga L. with nitric oxide inhibitory activity.Natural products and bioprospecting · 2025Article
- Substrate Preorganization Within Photoactive PtAngewandte Chemie (International ed. in English) · 2025Article
- Enantioselective dearomative ortho-cycloaddition transformation of unactivated arenes by cage-confined visible-light photocatalysis.Nature communications · 2025Article
- Ultrasmall radical metal organic cage as cascade antioxidant nanozyme for renal injury.Theranostics · 2025Article
- Double-Bridging Increases the Stability of Zinc(II) Metal-Organic Cages.Journal of the American Chemical Society · 2024Article
- Challenges and Future Perspectives in Photocatalysis: Conclusions from an Interdisciplinary Workshop.JACS Au · 2024Review
- "On-Water" accelerated dearomative cycloaddition via aquaphotocatalysis.Nature communications · 2024Article
- An artificial light-harvesting system constructed from a water-soluble metal-organic barrel for photocatalytic aerobic reactions in aqueous media.Chemical science · 2023Article
- Biomimetic Photodegradation of Glyphosate in Carborane-Functionalized Nanoconfined Spaces.Journal of the American Chemical Society · 2023Article
- Photocatalysis in Water-Soluble Supramolecular Metal Organic Complex.Molecules (Basel, Switzerland) · 2023Review
- Supramolecular Coordination Cages for Artificial Photosynthesis and Synthetic Photocatalysis.Chemical reviews · 2023Review
- Highly efficient Förster resonance energy transfer between an emissive tetraphenylethylene-based metal-organic cage and the encapsulated dye guest.Chemical science · 2023Article
- X-H Bond Insertion Promoted by Heterogeneous Dirhodium Metal-Organic Cage with Alkynes as Safe Carbene Precursors.Molecules (Basel, Switzerland) · 2023Article
- Photomechanochemical control over stereoselectivity in the [2 + 2] photodimerization of acenaphthylene.Faraday discussions · 2023Article
- Combining iminium and supramolecular catalysis for the [4 + 2] cycloaddition ofOrganic & biomolecular chemistry · 2022Article
- Controllable multiple-step configuration transformations in a thermal/photoinduced reaction.Nature communications · 2022Article
- Acidic open-cage solution containing basic cage-confined nanospaces for multipurpose catalysis.National science review · 2022Article
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Authors and funding
9 authors.
Funding
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Abstract
Light-induced [2 + 2] cycloaddition is the most straightforward way to generate cyclobutanes, which are core structures of many natural products, drugs and bioactive compounds. Despite continuous advances in selective [2 + 2] cycloaddition research, general method for intermolecular photocatalysis of acyclic olefins with specific regio- and diastereoselectivity, for example, syn-head-to-head (syn-HH) cyclobutane derivatives, is still lack of development but highly desired. Herein, we report a cage-confined photocatalytic protocol to enable unusual intermolecular [2 + 2] cycloaddition for α,β-unsaturated carbonyl compounds. The syn-HH diastereomers are readily generated with diastereoselectivity up to 99%. The cage-catalyst is highly efficient and robust, covering a diverse substrate range with excellent substituent tolerance. The mimic-enzyme catalysis is proposed through a host-guest mediated procedure expedited by aqueous phase transition of reactant and product, where the supramolecular cage effect plays an important role to facilitate substrates inclusion and pre-orientation, offering a promising avenue for general and eco-friendly cycloaddition photocatalysis with special diastereoselectivity.
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