ArticleThe Journal of organic chemistry2020
Examination of the Dynamic Covalent Chemistry of [2 + 3]-Imine Cages.
Article in The Journal of organic chemistry, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 13 papers.
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Who cites it
13 citing papers in PubMed.
- Self-assembled [2 + 3] organic-imine cage as an artificial light harvester for the photocatalytic organic transformation in an aqueous medium.RSC advances · 2025Article
- Structural control of dynamic covalent cages: kineticChemical science · 2025Article
- Kinetic Trapping of Rylene Diimide Covalent Organic Cages.The Journal of organic chemistry · 2025Article
- Transfer of structural units through imine exchanges, in solution or without solvent: successive transiminations, stimuli (pH)-modulated covalent switches, and mathematical models.Frontiers in chemistry · 2025Article
- Dynamic covalent synthesis.Chemical science · 2024Review
- Dimeric and trimeric catenation of giant chiral [8 + 12] imine cubes driven by weak supramolecular interactions.Nature chemistry · 2023Article
- [2+3] Amide Cages by Oxidation of [2+3] Imine Cages - Revisiting Molecular Hosts for Highly Efficient Nitrate Binding.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Purely Covalent Molecular Cages and Containers for Guest Encapsulation.Chemical reviews · 2022Review
- Dynamic Nucleophilic Aromatic Substitution of Tetrazines.Angewandte Chemie (International ed. in English) · 2021Article
- Soluble Congeners of Prior Insoluble Shape-Persistent Imine Cages.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- Supramolecular Alloys from Fluorinated Hybrid TriChemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- Chiral Self-sorting of Giant Cubic [8+12] Salicylimine Cage Compounds.Angewandte Chemie (International ed. in English) · 2021Article
- Endohedral Hydrogen Bonding Templates the Formation of a Highly Strained Covalent Organic Cage Compound*.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
Corrections and comments
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Authors and funding
3 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The synthesis of shape-persistent organic cage compounds by the formation of imine bonds opens the possibility to realize cages of different sizes, geometries, topologies, and functions. It is generally assumed that the imine bond is rather chemically labile allowing a self-correction mechanism until thermodynamic equilibrium is reached, which is often the case if a cage is formed. However, there are some contradictory experimental data to this assumption. To get a deeper insight into the imine bond dynamics of covalent organic cages, we studied the formation and exchange of both dialdehydes and triamines of two different [2 + 3] imine cages with the aid of a deuterated dialdehyde molecular building block.
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