ReviewAngewandte Chemie (International ed. in English)2021
Frustrated Radical Pairs: Insights from EPR Spectroscopy.
Review in Angewandte Chemie (International ed. in English), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 28 papers.
What it found
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Who cites it
28 citing papers in PubMed.
- Rotational observation of kinetically hindered neutral radical pairs.Nature communications · 2026Article
- Phosphine-catalyzed β-C(spChemical science · 2026Article
- Recent Advances in Heterogeneous Frustrated Lewis Pair: Synthesis, Characterization, and Catalysis.Advanced materials (Deerfield Beach, Fla.) · 2025Review
- Theoretical evaluation of the biological activity of hydrogen.Medical gas research · 2025Review
- Abstraction of Hydride from Alkanes and Dihydrogen by the Perfluorotrityl Cation.Angewandte Chemie (International ed. in English) · 2025Article
- Heterogeneous Frustrated Lewis Pair Catalysts: Rational Structure Design and Mechanistic Elucidation Based on Intrinsic Properties of Supports.Accounts of chemical research · 2025Article
- Synthesis and Photochemical Uncaging of Alkene-Protected, Polymer-Bound Vicinal Frustrated Lewis Pairs.Journal of the American Chemical Society · 2024Article
- Stable organic radical qubits and their applications in quantum information science.Innovation (Cambridge (Mass.)) · 2024Review
- Use of Microwave Dielectric Spectroscopy for theJournal of the American Chemical Society · 2024Article
- Mechanistic studies on single-electron transfer in frustrated Lewis pairs and its application to main-group chemistry.Chemical Society reviews · 2024Review
- Cross-coupling of organic fluorides with allenes: a silyl-radical-relay pathway for the construction of α-alkynyl-substituted all-carbon quaternary centres.Chemical science · 2024Article
- Single electron reduction of NHC-COChemical science · 2024Article
- Advances in COChemical science · 2023Review
- Light-Induced Polymeric Frustrated Radical Pairs as Building Blocks for Materials and Photocatalysts.Journal of the American Chemical Society · 2023Article
- Frustrated Radical Pairs in Organic Synthesis.Journal of the American Chemical Society · 2023Review
- Insights into Single-Electron-Transfer Processes in Frustrated Lewis Pair Chemistry and Related Donor-Acceptor Systems in Main Group Chemistry.Chemical reviews · 2023Review
- Atom-economic and stereoselective catalytic synthesis of fully substituted enol esters/carbonates of amides in acyclic systems enabled by boron Lewis acid catalysis.Chemical science · 2023Article
- Synthesis of triarylmethanes by silyl radical-mediated cross-coupling of aryl fluorides and arylmethanes.Chemical science · 2023Article
- Transition-metal-free silylboronate-mediated cross-couplings of organic fluorides with amines.Nature communications · 2023Article
- Generation of boryl-nitroxide radicals from a boraalkeneChemical science · 2022Article
Corrections and comments
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Authors and funding
3 authors.
Funding
Abstract
Progress in frustrated Lewis pair (FLP) chemistry has revealed the importance of the main group elements in catalysis, opening new avenues in synthetic chemistry. Recently, new reactivities of frustrated Lewis pairs have been uncovered that disclose that certain combinations of Lewis acids and bases undergo single-electron transfer (SET) processes. Here an electron can be transferred from the Lewis basic donor to a Lewis acidic acceptor to generate a reactive frustrated radical pair (FRP). This minireview aims to showcase the recent advancements in this emerging field covering the synthesis and reactivities of frustrated radical pairs, with extensive highlights of the results from Electron Paramagnetic Resonance (EPR) spectroscopy to explain the nature and stability of the different radical species observed.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.