ArticleThe journal of physical chemistry letters2020
The Bending Mode of Water: A Powerful Probe for Hydrogen Bond Structure of Aqueous Systems.
Article in The journal of physical chemistry letters, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 85 papers.
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Who cites it
85 citing papers in PubMed.
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- Characterizing the Anisotropic Elastic Properties of Auxetic Structures by Impulse Excitation Technique Combined with Inverse Parameter Identification.Materials (Basel, Switzerland) · 2026Article
- Sub-diffractional infrared absorption of two-dimensional water.Nature communications · 2026Article
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- Unveiling the atomic-scale mechanism of water-induced wettability transition in ZnO nanopods: a combined experimental and molecular dynamics study.Scientific reports · 2026Article
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- Mechanism of Vapor-Phase Infiltration of Organometallic Hf in Poly(Methyl Methacrylate) for Hybrid Resist Applications.Chemistry of materials : a publication of the American Chemical Society · 2026Article
- Water-Splitting "Without Water": Splitting of the Crystallised Water of Hydrated Salts.Angewandte Chemie (International ed. in English) · 2026Article
- Is Digital Drying an Effective Method for Infrared Spectroscopy of Gaseous Biofluid?Analytical chemistry · 2025Article
- Electrical Conductivity and Permittivity of Porous Media: Origin, Measurements, and Implications.ACS measurement science au · 2025Review
- Lactoferrin based copper nanoparticles: a promising anti-cancer strategy against malignant melanoma.Scientific reports · 2025Article
25 more citing papers are in PubMed but not listed here.
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Authors and funding
8 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Insights into the microscopic structure and dynamics of the water's hydrogen-bonded network are crucial to understand the role of water in biology, atmospheric and geochemical processes, and chemical reactions in aqueous systems. Vibrational spectroscopy of water has provided many such insights, in particular using the O-H stretch mode. In this Perspective, we summarize our recent studies that have revealed that the H-O-H bending mode can be an equally powerful reporter for the microscopic structure of water and provides more direct access to the hydrogen-bonded network than the conventionally studied O-H stretch mode. We discuss the fundamental vibrational properties of the water bending mode, such as the intermolecular vibrational coupling, and its effects on the spectral lineshapes and vibrational dynamics. Several examples of static and ultrafast bending mode spectroscopy illustrate how the water bending mode provides an excellent window on the microscopic structure of both bulk and interfacial water.
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Registered trials
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