ArticleAngewandte Chemie (International ed. in English)2020
Oxidative Addition of a Mechanically Entrapped C(sp)-C(sp) Bond to a Rhodium(I) Pincer Complex.
Article in Angewandte Chemie (International ed. in English), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.
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Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
10 citing papers in PubMed.
- One Step Synthesis of 4,6,8-Trimethoxyazulenes - as Building Block for 2-Functionalized Azulenes.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Kinetically controlled synthesis of rotaxane geometric isomers.Chemical science · 2024Article
- LNL-Carbazole Pincer Ligand: More than the Sum of Its Parts.Chemical reviews · 2023Review
- Modulation of Metal Carbonyl Stretching Frequencies in the Second Coordination Sphere through the Internal Stark Effect.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Anion-π Catalysis Enabled by the Mechanical Bond.Angewandte Chemie (International ed. in English) · 2022Article
- ηInorganic chemistry · 2021Article
- Rotaxane CoAngewandte Chemie (International ed. in English) · 2021Article
- Spin-labelled mechanically interlocked molecules as models for the interpretation of biradical EPR spectra.Chemical science · 2021Article
- The Fascinating Flexibility and Coordination Modes of a Pentamethylene Connected Macrocyclic CNC Pincer Ligand.Molecules (Basel, Switzerland) · 2021Article
- Oxidative Addition of a Mechanically Entrapped C(sp)-C(sp) Bond to a Rhodium(I) Pincer Complex.Angewandte Chemie (International ed. in English) · 2020Article
Corrections and comments
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Authors and funding
3 authors.
Funding
Abstract
By use of a macrocyclic phosphinite pincer ligand and bulky substrate substituents, we demonstrate how the mechanical bond can be leveraged to promote the oxidative addition of an interlocked 1,3-diyne to a rhodium(I) center. The resulting rhodium(III) bis(alkynyl) product can be trapped out by reaction with carbon monoxide or intercepted through irreversible reaction with dihydrogen, resulting in selective hydrogenolysis of the C-C σ-bond.
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Registered trials
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