Evidence map›Paper›PMID 32917679›Full record

ArticleScience advances2020

High-sensitivity nanoscale chemical imaging with hard x-ray nano-XANES.

A Pattammattel, R Tappero, M Ge, Y S Chu, X Huang, Y Gao, H Yan

Abstract read
In one paragraph

Article in Science advances, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 23 papers.

0numbers the graph read from it
0cells of the map it votes in
23citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

23 citing papers in PubMed.

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  14. Nanoscale chemical imaging with structured X-ray illumination.Proceedings of the National Academy of Sciences of the United States of America · 2023
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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors.

A PattammattelNational Synchrotron Light Source II, Brookhaven National Laboratory, Upton, NY, USA.ORCID http://orcid.org/0000-0002-5956-7808
R TapperoNational Synchrotron Light Source II, Brookhaven National Laboratory, Upton, NY, USA.ORCID http://orcid.org/0000-0002-3560-2461
M GeNational Synchrotron Light Source II, Brookhaven National Laboratory, Upton, NY, USA.ORCID http://orcid.org/0000-0001-5682-7443
Y S ChuNational Synchrotron Light Source II, Brookhaven National Laboratory, Upton, NY, USA.
X HuangNational Synchrotron Light Source II, Brookhaven National Laboratory, Upton, NY, USA.ORCID http://orcid.org/0000-0001-6034-5893
Y GaoNational Synchrotron Light Source II, Brookhaven National Laboratory, Upton, NY, USA.ORCID http://orcid.org/0000-0002-5435-8863
H YanNational Synchrotron Light Source II, Brookhaven National Laboratory, Upton, NY, USA. hyan@bnl.gov.ORCID http://orcid.org/0000-0001-6824-0367

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Resolving chemical species at the nanoscale is of paramount importance to many scientific and technological developments across a broad spectrum of disciplines. Hard x-rays with excellent penetration power and high chemical sensitivity are suitable for speciation of heterogeneous (thick) materials. Here, we report nanoscale chemical speciation by combining scanning nanoprobe and fluorescence-yield x-ray absorption near-edge structure (nano-XANES). First, the resolving power of nano-XANES was demonstrated by mapping Fe(0) and Fe(III) states of a reference sample composed of stainless steel and hematite nanoparticles with 50-nm scanning steps. Nano-XANES was then used to study the trace secondary phases in lithium iron phosphate (LFP) particles. We observed individual Fe-phosphide nanoparticles in pristine LFP, whereas partially (de)lithiated particles showed Fe-phosphide nanonetworks. These findings shed light on the contradictory reports on Fe-phosphide morphology in the literature. Nano-XANES bridges the capability gap of spectromicroscopy methods and provides exciting research opportunities across multiple disciplines.

Identifiers

PMID32917679
PMCPMC11206466

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.