ReviewACS catalysis2020
Phosphoranyl Radical Fragmentation Reactions Driven by Photoredox Catalysis.
Review in ACS catalysis, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 45 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
45 citing papers in PubMed.
- Photocatalytic synthesis of phosphorothioates by sulfur transfer from thiosulfate.Chemical science · 2026Article
- Cobalt-catalyzed Markovnikov-selective hydrophosphonylation of unactivated alkenes enabled by phthalimidyl phosphite reagents.Nature communications · 2026Article
- Origin of Scission Selectivity for Phosphoranyl Radicals in Photoredox Catalysis.Journal of the American Chemical Society · 2026Article
- Electrochemically driven deoxychlorination of aliphatic alcoholsChemical science · 2026Article
- Phosphoryl Radicals from Trivalent Iminyl Phosphines: A Photocatalytic Approach to N-Phosphoryl Azetidines.Angewandte Chemie (International ed. in English) · 2026Article
- Redirecting radical phosphonylation via energy-transfer-enabled diradical rearrangement.Science advances · 2026Article
- Iron-Photocatalyzed C(spAngewandte Chemie (International ed. in English) · 2026Article
- TiOACS nanoscience Au · 2026Article
- Catalytic Markovnikov hydrophosphorylation of unactivated olefins via a radical-polar crossover rearrangement.Nature communications · 2026Article
- Deoxygenative phosphonation of ketones by titanium.Chemical science · 2026Article
- Article
- Activation of Cyanate Anions by Phosphine Radical Cations Enables Formal Hydrocarbamoylation of Alkenes.Angewandte Chemie (International ed. in English) · 2026Article
- Metal-Free Direct Electrochemical Deoxygenation of Benzylic Alcohols.ACS sustainable chemistry & engineering · 2025Article
- Direct deoxygenative arylation of saccharides via phosphorus-assisted C-OH bond activation.Nature communications · 2025Article
- Photocatalytic generation of amidine carbon radicals for aminodihydroquinoline synthesis.Nature communications · 2025Article
- Building From the Ground Up: A Procedural Guide to Locally Controlling Bond Exchange Kinetics in Dynamic Thiol-Thioester Networks.Macromolecular rapid communications · 2025Article
- Visible light promotes PACS catalysis · 2025Article
- Catalytic ammonia formation from dinitrogen, water, and visible light energy.Nature communications · 2025Article
- Hexaphenyl-1,2-Diphosphonium Dication [PhJournal of the American Chemical Society · 2025Article
- Generation of Oxyphosphonium Ions by Photoredox/Cobaloxime Catalysis for Scalable Amide and Peptide Synthesis in Batch and Continuous Flow.Methods in molecular biology (Clifton, N.J.) · 2025Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
4 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Photocatalytic generation of phosphoranyl radicals is fast emerging as an essential method for the generation of diverse and valuable radicals, typically via deoxygenation or desulfurization processes. This Perspective is a comprehensive evaluation of all studies using phosphoranyl radicals as tunable mediators in photoredox catalysis, highlighting how two distinct methods for phosphoranyl radical formation (radical addition and nucleophilic addition) can be used to generate versatile radical intermediates with diverse reactivity profiles.
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.