Evidence map›Paper›PMID 32866305›Full record

ArticleAngewandte Chemie (International ed. in English)2021

Beyond the Classical Electron-Sharing and Dative Bond Picture: Case of the Spin-Polarized Bond.

Pedro Salvador, Eva Vos, Inés Corral, Diego M Andrada

Abstract read
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 14 papers.

0numbers the graph read from it
0cells of the map it votes in
14citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

14 citing papers in PubMed.

  1. Article
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  4. Modulation of the Product Upon the Reaction of COJournal of computational chemistry · 2025
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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors.

Pedro SalvadorInstitut de Química Computacional i Catàlisi i Departament de Química, Universitat de Girona, c/M Aurelia Capmany 69, 17003, Girona, Spain.
Eva VosDepartamento de Química, Facultad de Ciencias, Módulo 13, and Institute of Advanced Chemical Sciences (IadChem), Universidad Autónoma de Madrid, Campus de Excelencia UAM-CSIC, Cantoblanco, 28049, Madrid, Spain.
Inés CorralDepartamento de Química, Facultad de Ciencias, Módulo 13, and Institute of Advanced Chemical Sciences (IadChem), Universidad Autónoma de Madrid, Campus de Excelencia UAM-CSIC, Cantoblanco, 28049, Madrid, Spain.
Diego M AndradaFaculty of Natural Sciences and Technology, Department of Chemistry, Saarland University, 66123, Saarbrücken, Germany.ORCID http://orcid.org/0000-0003-2515-7859

Funding

H2020 European Research Council 805113Ministerio de Ciencia, Innovación y Universidades PGC2018-094644-B-C21Ministerio de Ciencia, Innovación y Universidades PGC2018-098212-B-C22Ramón y Cajal RYC-2016-20489
6 · The paper itself

Abstract

Chemical bonds are traditionally assigned as electron-sharing or donor-acceptor/dative. External criteria such as the nature of the dissociation process, energy partitioning schemes, or quantum chemical topology are invoked to assess the bonding situation. However, for systems with marked multi-reference character, this binary categorization might not be precise enough to render the bonding properties. A third scenario can be foreseen: spin polarized bonds. To illustrate this, the case of a NaBH

Indexed as

bond analysisdative bondsdonor-acceptor systemselectronic structuresodium

Identifiers

PMID32866305
PMCPMC7839703

What OpenQuestion holds

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.