ArticleCoordination chemistry reviews2020
Reactivity of terminal imido complexes of group 4-6 metals: stoichiometric and catalytic reactions involving cycloaddition with unsaturated organic molecules.
Article in Coordination chemistry reviews, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 16 papers.
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Who cites it
16 citing papers in PubMed, 76 citations in OpenAlex.
- A Series of Trigonal Arylimido Iron Complexes and the Influence of Oxidation State and Steric Demand on Reactivity.Inorganic chemistry · 2025Article
- Carbon Dioxide Capture and Functionalization from a Molecular Ti(III) Oxo Anion.Angewandte Chemie (International ed. in English) · 2025Article
- Alkyne Carboamination with Imines Catalyzed by [pyOrganometallics · 2025Article
- Bonding and Reactivity of dJournal of the American Chemical Society · 2024Article
- A mononuclear, terminal titanium(III) imido.Chemical communications (Cambridge, England) · 2023Article
- Synthesis of Ti Complexes Supported by an ortho-terphenoxide Ligand and their Applications in Alkyne Hydroamination Catalysis.Organometallics · 2023Article
- Ti-Catalyzed Multicomponent Synthesis of Pyrroles Using Allene Coupling Partners.Organometallics · 2023Article
- Reactivity and Structure of a Bis-phenolate Niobium NHC Complex.ACS organic & inorganic Au · 2023Article
- Engendering reactivity at group 5-heteroatom multiple bondsChemical science · 2022Review
- Between imide, imidyl and nitrene - an imido iron complex in two oxidation states.Chemical science · 2022Article
- α-Diimine synthesisChemical science · 2022Article
- N═N Bond Cleavage by Tantalum Hydride Complexes: Mechanistic Insights and Reactivity.Inorganic chemistry · 2022Article
- Selective propargylic C(spChemical science · 2021Article
- Ti-Catalyzed and -Mediated Oxidative Amination Reactions.Accounts of chemical research · 2021Article
- A Terminal Imido Complex of an Iron-Sulfur Cluster.Angewandte Chemie (International ed. in English) · 2021Article
- 1,2-Addition and cycloaddition reactions of niobium bis(imido) and oxo imido complexes.Chemical science · 2020Article
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Authors and funding
7 authors at 3 institutions in 2 countries.
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Abstract
Imido complexes of early transition metals are key intermediates in the synthesis of many nitrogen-containing organic compounds. The metal-nitrogen double bond of the imido moiety undergoes [2+2] cycloaddition reactions with various unsaturated organic molecules to form new nitrogen-carbon and nitrogen-heteroatom bonds. This review article focuses on reactivity of the terminal imido complexes of Group 4-6 metals, summarizing their stoichiometric reactions and catalytic applications for a variety of reactions including alkyne hydroamination, alkyne carboamination, pyrrole formation, imine metathesis, and condensation reactions of carbonyl compounds with isocyanates.
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