ArticleAngewandte Chemie (International ed. in English)2020
A New Mechanically-Interlocked [Pd
Article in Angewandte Chemie (International ed. in English), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 20 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
20 citing papers in PubMed, 42 citations in OpenAlex.
- Tangled Tail of Mechanically Interlocked Peptides.Journal of the American Chemical Society · 2026Review
- An Organometallic [2]Catenane With Pt‒(di-NHC)‒Pt Units: A Topology-Driven Strategy for Enhanced Phosphorescence in Discrete Aggregates.Angewandte Chemie (International ed. in English) · 2026Article
- Peptide cages: bioinspired supramolecular architectures for next-generation applications.Chemical science · 2026Review
- Dynamic Reconfiguration of Pt(II) Supramolecular Assemblies via Ligand Exchange.ACS applied materials & interfaces · 2025Article
- Crown Ether-Peptide Rotaxanes.Angewandte Chemie (International ed. in English) · 2025Article
- Embracing Complexity: Peptides as Tunable Scaffolds in the Construction of Discrete Supramolecular Systems.Angewandte Chemie (International ed. in English) · 2025Review
- Effective RNA Complexation by [2]Catenanes Confers Enhanced Resistance to Enzymatic Degradation.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Topological variety and self-sorting in homo- and heteroleptic PdChemical science · 2025Review
- Intricate Low-Symmetry AgJournal of the American Chemical Society · 2024Article
- High-order layered self-assembled multicavity metal--organic capsules and anti-cooperative host-multi-guest chemistry.Chemical science · 2024Article
- Article
- Guest-Modulated Circularly Polarized Luminescence by Ligand-to-Ligand Chirality Transfer in Heteroleptic PdAngewandte Chemie (International ed. in English) · 2022Article
- Transformation networks of metal-organic cages controlled by chemical stimuli.Chemical Society reviews · 2022Review
- Beyond Platonic: How to Build Metal-Organic Polyhedra Capable of Binding Low-Symmetry, Information-Rich Molecular Cargoes.Chemical reviews · 2022Review
- Cagearenes: synthesis, characterization, and application for programmed vapour release.Chemical science · 2022Article
- Ion Mobility Mass Spectrometry Uncovers Guest-Induced Distortions in a Supramolecular Organometallic Metallosquare.Angewandte Chemie (International ed. in English) · 2021Article
- Increasing structural and functional complexity in self-assembled coordination cages.Chemical science · 2021Review
- Integrative Assembly of Heteroleptic Tetrahedra Controlled by Backbone Steric Bulk.Journal of the American Chemical Society · 2021Article
- Visible-Light-Driven Rotation of Molecular Motors in Discrete Supramolecular Metallacycles.Journal of the American Chemical Society · 2021Article
- A New Mechanically-Interlocked [PdAngewandte Chemie (International ed. in English) · 2020Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
6 authors at 2 institutions in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Most metallo-supramolecular assemblies of low nuclearity adopt simple topologies, with bridging ligands spanning neighboring metal centers in a direct fashion. Here we contribute a new structural motif to the family of host compounds with low metal count (two) that consists of a pair of doubly-interlocked, Figure-eight-shaped subunits, also termed "lemniscates". Each metal is chelated by two chiral bidentate ligands, composed of a peptidic macrocycle that resembles a natural product with two pyridyl-terminated arms. DFT calculation results suggest that dimerization of the mononuclear halves is driven by a combination of 1) Coulomb interaction with a central anion, 2) π-stacking between intertwined ligand arms and 3) dispersive interactions between the structure's compact inner core bedded into an outer shell composed of the cavitand-type macrocycles. The resulting cage-like architecture was characterized by NMR, MS and X-ray structure analyses. This new mechanically bonded system highlights the scope of structural variety accessible in metal-mediated self-assemblies composed of only a few constituents.
Indexed as
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.