Evidence map›Paper›PMID 32840947›Full record

ArticleAngewandte Chemie (International ed. in English)2020

Single-Electron Transfer in Frustrated Lewis Pair Chemistry.

Flip Holtrop, Andrew R Jupp, Bastiaan J Kooij, Nicolaas P van Leest, Bas de Bruin, J Chris Slootweg

Abstract read
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 24 papers.

0numbers the graph read from it
0cells of the map it votes in
24citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

24 citing papers in PubMed.

  1. Review
  2. Hexaphenyl-1,2-Diphosphonium Dication [PhJournal of the American Chemical Society · 2025
    Article
  3. Article
  4. Article
  5. Article
  6. Article
  7. Article
  8. Single electron reduction of NHC-COChemical science · 2024
    Article
  9. Article
  10. Frustrated Radical Pairs in Organic Synthesis.Journal of the American Chemical Society · 2023
    Review
  11. Review
  12. Article
  13. Article
  14. Article
  15. Article
  16. Article
  17. Piers' Borane-Induced Tetramerization of Arylacetylenes.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022
    Article
  18. Article
  19. Phosphorus-Based Catalysis.ACS central science · 2021
    Review
  20. Site-Selective CJournal of the American Chemical Society · 2021
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors.

Flip HoltropVan't Hoff Institute for Molecular Sciences, University of Amsterdam, PO Box 94157, 1090 GD, Amsterdam, The Netherlands.ORCID http://orcid.org/0000-0002-6225-1847
Andrew R JuppVan't Hoff Institute for Molecular Sciences, University of Amsterdam, PO Box 94157, 1090 GD, Amsterdam, The Netherlands.ORCID http://orcid.org/0000-0003-4360-5838
Bastiaan J KooijVan't Hoff Institute for Molecular Sciences, University of Amsterdam, PO Box 94157, 1090 GD, Amsterdam, The Netherlands.
Nicolaas P van LeestVan't Hoff Institute for Molecular Sciences, University of Amsterdam, PO Box 94157, 1090 GD, Amsterdam, The Netherlands.
Bas de BruinVan't Hoff Institute for Molecular Sciences, University of Amsterdam, PO Box 94157, 1090 GD, Amsterdam, The Netherlands.
J Chris SlootwegVan't Hoff Institute for Molecular Sciences, University of Amsterdam, PO Box 94157, 1090 GD, Amsterdam, The Netherlands.ORCID http://orcid.org/0000-0001-7818-7766

Funding

Nederlandse Organisatie voor Wetenschappelijk Onderzoek NWA.1228.191.330
6 · The paper itself

Abstract

Frustrated Lewis pairs (FLPs) are well known for their ability to activate small molecules. Recent reports of radical formation within such systems indicate single-electron transfer (SET) could play an important role in their chemistry. Herein, we investigate radical formation upon reacting FLP systems with dihydrogen, triphenyltin hydride, or tetrachloro-1,4-benzoquinone (TCQ) both experimentally and computationally to determine the nature of the single-electron transfer (SET) events; that is, being direct SET to B(C

Indexed as

frustrated Lewis pairsradicalsreactivitysingle-electron transfersubstrate coordination

Identifiers

PMID32840947
PMCPMC7756365

What OpenQuestion holds

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LicenceCC BY-NC-ND
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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.