ArticleChemistry (Weinheim an der Bergstrasse, Germany)2021
A Giant [8+12] Boronic Ester Cage with 48 Terminal Alkene Units in the Periphery for Postsynthetic Alkene Metathesis.
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.
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Who cites it
5 citing papers in PubMed.
- Synthesis and Optoelectronic Properties of Threaded BODIPYs.ChemistryOpen · 2024Article
- A Water-Stable Boronate Ester Cage.Journal of the American Chemical Society · 2024Article
- Porous Organic Cages.Chemical reviews · 2023Review
- Cucurbitimines - imine cages with concave walls.Organic chemistry frontiers : an international journal of organic chemistry · 2021Article
- A Giant [8+12] Boronic Ester Cage with 48 Terminal Alkene Units in the Periphery for Postsynthetic Alkene Metathesis.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
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2 authors.
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Abstract
Dynamic covalent chemistry (DCC) is a powerful synthetic tool to construct large defined molecules in one step from rather simple precursors. The advantage of the intrinsic dynamics of the applied reversible reaction steps is a self-correction under the chosen conditions, to achieve high yields of the target compound. To date, only a few examples are known, in which DCC was used to build up a molecular defined but larger product that was chemically transferred to a more stable congener in a second (irreversible) step. Here, we present a nanometer-sized [8+12] boronic ester cage containing 48 peripheral terminal alkene units which allows to put a hydrocarbon exoskeleton around the cage via alkene metathesis.
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