ArticleNature chemistry2020
A platinum(II) metallonitrene with a triplet ground state.
Article in Nature chemistry, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. An erratum has been issued. Cited by 43 papers.
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Who cites it
43 citing papers in PubMed.
- Efficient COMolecules (Basel, Switzerland) · 2026Article
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- A gold nitrene for nitrogen-atom transfer chemistry.Nature chemistry · 2026Article
- Crystalline nitrogen chain radical anions.Nature chemistry · 2026Article
- X-ray activated platinum complex induces DNA damage and enhances cancer immunotherapy through abscopal effect.Nature biomedical engineering · 2026Article
- Gold(III)-Substituted Carbenes.Journal of the American Chemical Society · 2026Article
- Triplet Metallovinylidenes of Palladium and Platinum Based on a Chelating P/Diazoalkene Ligand.Angewandte Chemie (International ed. in English) · 2026Article
- Nitrogen Subvalency in a Four-Member Redox Series of Iron-Sulfur Cluster Imido Complexes.Journal of the American Chemical Society · 2025Article
- Synthesis and Reactivity of a Mono-Coordinated Triplet Bismuthinidene.Angewandte Chemie (International ed. in English) · 2025Article
- Historical and Recent Developments in the Chemistry of Cyanate Congeners.Inorganic chemistry · 2025Review
- Diverging Reactivity in Anilidophosphine Supported Group III Complexes.Chemistry, an Asian journal · 2025Article
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- 4f-orbital covalency enables a single-crystal-to-single-crystal ring-opening isomerization in a CeNature chemistry · 2025Article
- Catalytic Amino Group Transfer Reactions Mediated by Photoinduced Nitrene Formation from Rhodium-Hydroxamates.Angewandte Chemie (International ed. in English) · 2025Article
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- P-P CouplingJournal of the American Chemical Society · 2025Article
- Transient Triplet Metallopnictinidenes M-Pn (M = PdJournal of the American Chemical Society · 2025Article
- An Open-Shell FeJournal of the American Chemical Society · 2025Article
- Direct Determination of a Giant Zero-Field Splitting of 5422 cmJournal of the American Chemical Society · 2025Article
Corrections and comments
- Erratum issued
Authors and funding
10 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Metallonitrenes (M-N) are complexes with a subvalent atomic nitrogen ligand that have been proposed as key reactive intermediates in nitrogen atom transfer reactions. However, in contrast to the common classes of nitride complexes (M≡N) and organic nitrenes (R-N), structurally and spectroscopically well defined 'authentic' metallonitrenes with a monovalent atomic nitrogen ligand remain elusive. Here we report that the photolysis of a platinum(II) pincer azide complex enabled the crystallographic, spectroscopic, magnetic and computational characterization of a metallonitrene that is best described as a singly bonded atomic nitrogen diradical ligand bound to platinum(II). The photoproduct exhibits selective C-H, B-H and B-C nitrogen atom insertion reactivity. Despite the subvalent metallonitrene character, mechanistic analysis for aldehyde C-H amidation shows nucleophilic reactivity of the N-diradical ligand. Ambiphilic reactivity of the metallonitrene is indicated by reactions with CO and PMe
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