ArticleThe Journal of organic chemistry2020
Stereochemical Inversion of Rim-Differentiated Pillar[5]arene Molecular Swings.
Article in The Journal of organic chemistry, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 9 papers.
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Who cites it
9 citing papers in PubMed.
- Beyond Passive Substituents: Tosyl-Directed Self-Templation Enables Selective Pillar[4 + 1]arene Formation and Topology Switching.Journal of the American Chemical Society · 2026Article
- Enantioselective sensing driven by the interplay of point, helical and planar chirality in pillar[5]arene Pseudo[1]catenanes.Communications chemistry · 2025Article
- Guest-Induced Conformational Transformations in Tiara[5]arene Crystals: A Pathway for Molecular Sieving.JACS Au · 2024Article
- Pillar[5]arenes decorated with six-membered-ring aromatics at all the substitution positions.Chemical science · 2024Article
- Real-time chirality transfer monitoring from statistically random to discrete homochiral nanotubes.Nature communications · 2022Article
- Cyclic arrays of five pyrenes on one rim of a planar chiral pillar[5]arene.Chemical science · 2022Article
- CPL on/off control of an assembled system by water soluble macrocyclic chiral sources with planar chirality.Chemical science · 2022Article
- Spontaneous and induced chiral symmetry breaking of stereolabile pillar[5]arene derivatives upon crystallisation.Chemical science · 2021Article
- An intramolecularly self-templated synthesis of macrocycles: self-filling effects on the formation of prismarenes.Chemical science · 2021Article
Corrections and comments
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Authors and funding
10 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
To investigate the dynamic stereochemical inversion behavior of pillar[5]arenes (P[5]s) in more detail, we synthesized a series of novel rim-differentiated P[5]s with various substituents and examined their rapid rotations by variable-temperature NMR (203-298 K). These studies revealed for the first time the barrier of "methyl-through-the-annulus" rotation (Δ
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Registered trials
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