ArticleAngewandte Chemie (International ed. in English)2020
The Mystery of the Benzene-Oxide/Oxepin Equilibrium-Heavy-Atom Tunneling Reversed by Solvent Interactions.
Article in Angewandte Chemie (International ed. in English), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 13 papers.
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Who cites it
13 citing papers in PubMed, 33 citations in OpenAlex.
- Solvation or not solvation: tunneling reactions of molecules embedded in cryogenic matrices.Chemical science · 2026Article
- Exceptions, Paradoxes, and Their Resolutions in Chemical Reactivity.The Journal of organic chemistry · 2024Review
- Norcaradiene-Cycloheptatriene Equilibrium: A Heavy-Atom Quantum Tunneling Case.The Journal of organic chemistry · 2024Article
- The Intrinsic Barrier Width and Its Role in Chemical Reactivity.ACS central science · 2023Article
- First-Principles Study of the Dispersion Effects in the Structures and Keto-Enol Tautomerization of Curcumin.ACS omega · 2023Article
- Differential Tunneling-Driven and Vibrationally-Induced Reactivity in Isomeric Benzazirines.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Simultaneous Tunneling Control in Conformer-Specific Reactions.Journal of the American Chemical Society · 2022Article
- Transformations of Strained Three-Membered Rings a Common, Yet Overlooked, Motif in Heavy-Atom Tunneling Reactions.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Stereoelectronic and dynamical effects dictate nitrogen inversion during valence isomerism in benzene imine.Chemical science · 2022Article
- Lewis acid catalyzed heavy atom tunneling - the case of 1Chemical science · 2021Article
- Article
- Switch chemistry at cryogenic conditions: quantum tunnelling under electric fields.Chemical science · 2020Article
- The Mystery of the Benzene-Oxide/Oxepin Equilibrium-Heavy-Atom Tunneling Reversed by Solvent Interactions.Angewandte Chemie (International ed. in English) · 2020Article
Corrections and comments
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Authors and funding
3 authors at 1 institution in 1 country.
Funding
Abstract
The equilibrium between benzene oxide (1) and oxepin (2) is of large importance for understanding the degradation of benzene in biological systems and in the troposphere. Our studies reveal that at cryogenic temperatures, this equilibration is governed by rare heavy-atom tunneling. In solid argon at 3 K, 1 rearranges to 2 via tunneling with a rate constant of approximately 5.3×10
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Registered trials
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