ArticleNature communications2020
Graphitic phosphorus coordinated single Fe atoms for hydrogenative transformations.
Article in Nature communications, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 22 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
22 citing papers in PubMed.
- Ru-enabled dehydration-reductive amination of α-, β-hydroxy acids into amino acids.Nature communications · 2026Article
- Upcycling Spent Lithium Iron Phosphate Battery Into Fe-CNAngewandte Chemie (International ed. in English) · 2026Article
- Enhancing Activation of DJACS Au · 2025Article
- High-Coordination and Nb-Bridging of Bimetallic Amorphous PAdvanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- Tandem reductive amination and deuteration over a phosphorus-modified iron center.Nature communications · 2025Article
- Implantable photoelectrochemical-therapeutic methotrexate monitoring system with dual-atomic docking strategy.Nature communications · 2025Article
- Topological transformation of microbial proteins into iron single-atom sites for selective hydrogen peroxide electrosynthesis.Nature communications · 2024Article
- Selective hydrogenation of vanillin over a graphene-encapsulated nitrogen-doped bimetallic magnetic Ni/Fe@NDC nano-catalyst.RSC advances · 2024Article
- Tailoring coordination environments of single-atom electrocatalysts for hydrogen evolution by topological heteroatom transfer.Nature communications · 2024Article
- A replacement strategy for regulating local environment of single-atom Co-SNature communications · 2024Article
- Operando analysis reveals potential-driven in situ formation of single-Fe-atom electrocatalysts for green production of ammonia.Proceedings of the National Academy of Sciences of the United States of America · 2023Article
- Atomic Cu-N-P-C Active Complex with Integrated Oxidation and Chlorination for Improved Ethylene Oxychlorination.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2023Article
- N, S Co-Coordinated Zinc Single-Atom Catalysts for N-Alkylation of Aromatic Amines with Alcohols: The Role of S-Doping in the Reaction.Nanomaterials (Basel, Switzerland) · 2023Article
- Spontaneous FeiScience · 2023Article
- Recent Advances in Carbon-Based Iron Catalysts for Organic Synthesis.Nanomaterials (Basel, Switzerland) · 2022Review
- Mild and Efficient Heterogeneous Hydrogenation of Nitroarenes Facilitated by a Pyrolytically Activated Dinuclear Ni(II)-Ce(III) Diimine Complex.International journal of molecular sciences · 2022Article
- Metal-Free Boron/Phosphorus Co-Doped Nanoporous Carbon for Highly Efficient Benzyl Alcohol Oxidation.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2022Article
- Unprecedentedly high activity and selectivity for hydrogenation of nitroarenes with single atomic CoNature communications · 2022Article
- Interactions between atomically dispersed copper and phosphorous species are key for the hydrochlorination of acetylene.Communications chemistry · 2022Article
- Atomically dispersed Fe atoms anchored on S and N-codoped carbon for efficient electrochemical denitrification.Proceedings of the National Academy of Sciences of the United States of America · 2021Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
9 authors.
Funding
Abstract
Single-atom metal-nitrogen-carbon (M-N-C) catalysts have sparked intensive interests, however, the development of an atomically dispersed metal-phosphorus-carbon (M-P-C) catalyst has not been achieved, although molecular metal-phosphine complexes have found tremendous applications in homogeneous catalysis. Herein, we successfully construct graphitic phosphorus species coordinated single-atom Fe on P-doped carbon, which display outstanding catalytic performance and reaction generality in the heterogeneous hydrogenation of N-heterocycles, functionalized nitroarenes, and reductive amination reactions, while the corresponding atomically dispersed Fe atoms embedded on N-doped carbon are almost inactive under the same reaction conditions. Furthermore, we find that the catalytic activity of graphitic phosphorus coordinated single-atom Fe sharply decreased when Fe atoms were transformed to Fe clusters/nanoparticles by post-impregnation Fe species. This work can be of fundamental interest for the design of single-atom catalysts by utilizing P atoms as coordination sites as well as of practical use for the application of M-P-C catalysts in heterogeneous catalysis.
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.