ArticleProceedings of the National Academy of Sciences of the United States of America2020
Electronic structure and photophysics of a supermolecular iron complex having a long MLCT-state lifetime and panchromatic absorption.
Article in Proceedings of the National Academy of Sciences of the United States of America, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 16 papers.
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Who cites it
16 citing papers in PubMed.
- Synthetic Mechanism of a Fe(II)Inorganic chemistry · 2026Article
- Homomolecular Photon Upconversion in a Perylene-Decorated Iron(III) Complex.Journal of the American Chemical Society · 2025Article
- Beyond Common Energy Transfer: Intramolecular Electron Transfer Cascade Controls Triplet Population of a Long-Lived Iron-Anthracene Molecular Dyad.ACS central science · 2025Article
- Structural Control of Metal-Centered Excited States in Cobalt(III) Complexes via Bite Angle and π-π Interactions.Journal of the American Chemical Society · 2025Article
- IronInorganic chemistry · 2025Article
- Iron(III) Complexes with Luminescence Lifetimes of up to 100 ns to Enhance Upconversion and Photocatalysis.Journal of the American Chemical Society · 2025Article
- Breaking the size limitation of nonadiabatic molecular dynamics in condensed matter systems with local descriptor machine learning.Proceedings of the National Academy of Sciences of the United States of America · 2024Article
- Iron(III) Carbene Complexes with Tunable Excited State Energies for Photoredox and Upconversion.Journal of the American Chemical Society · 2024Article
- Janus-type emission from a cyclometalated iron(III) complex.Nature chemistry · 2023Article
- Photoactive Metal-to-Ligand Charge Transfer Excited States in 3dJournal of the American Chemical Society · 2023Review
- Photophysical Integrity of the Iron(III) Scorpionate Framework in Iron(III)-NHC Complexes with Long-LivedInorganic chemistry · 2022Article
- Pseudo-Octahedral Iron(II) Complexes with Near-Degenerate Charge Transfer and Ligand Field States at the Franck-Condon Geometry.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Cobalt(III) Carbene Complex with an Electronic Excited-State Structure Similar to Cyclometalated Iridium(III) Compounds.Journal of the American Chemical Society · 2022Article
- The influence of alkyl chains on the performance of DSCs employing iron(II) N-heterocyclic carbene sensitizers.Dalton transactions (Cambridge, England : 2003) · 2021Article
- Ultrafast and long-time excited state kinetics of an NIR-emissive vanadium(iii) complex I: synthesis, spectroscopy and static quantum chemistry.Chemical science · 2021Article
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6 authors.
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No grant is acknowledged in the PubMed record.
Abstract
Exploiting earth-abundant iron-based metal complexes as high-performance photosensitizers demands long-lived electronically excited metal-to-ligand charge-transfer (MLCT) states, but these species suffer typically from femtosecond timescale charge-transfer (CT)-state quenching by low-lying nonreactive metal-centered (MC) states. Here, we engineer supermolecular Fe(II) chromophores based on the bis(tridentate-ligand)metal(II)-ethyne-(porphinato)zinc(II) conjugated framework, previously shown to give rise to highly delocalized low-lying
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