ArticleChemical reviews2021
Transition Metal-Catalyzed Selective Carbon-Carbon Bond Cleavage of Vinylcyclopropanes in Cycloaddition Reactions.
Article in Chemical reviews, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 34 papers.
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Who cites it
34 citing papers in PubMed, 313 citations in OpenAlex.
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- Cobalt-Catalyzed (3 + 2) Cycloaddition of Cyclopropene-Tethered Alkynes: Versatile Access to Bicyclic Cyclopentadienyl Systems and Their CpM Complexes.ACS catalysis · 2024Article
- Access to Cyclic Borates by Cu-Catalyzed Borylation of Unactivated Vinylcyclopropanes.Organic letters · 2024Article
- Visible-light-enabled stereoselective synthesis of functionalized cyclohexylamine derivativesChemical science · 2024Article
- Pd-Catalyzed Regioselective Cyclopropanation of 2-Substituted 1,3-Dienes.ACS organic & inorganic Au · 2023Article
- Palladium-catalysed enantio- and regioselective (3 + 2) cycloaddition reactions of sulfamidate imine-derived 1-azadienes towards spirocyclic cyclopentanes.Chemical science · 2023Article
- Palladium-catalyzed enantioselective rearrangement of dienyl cyclopropanes.Chemical science · 2023Article
- Unveiling the Chemistry and Synthetic Potential of Catalytic Cycloaddition Reaction of Allenes: A Review.Molecules (Basel, Switzerland) · 2023Review
- Organothianthrenium salts: synthesis and utilization.Chemical science · 2022Review
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Authors and funding
4 authors at 2 institutions in 2 countries.
Funding
Abstract
In this review, transition metal-catalyzed methodologies and applications that exploit C-C bond cleavage of vinylcyclopropanes (VCPs) are summarized with a focus on cycloaddition and related addition reactions. Transition metals, including palladium, nickel, iron, ruthenium, rhodium, cobalt, and iridium, can catalyze the cleavage of C-C bonds in activated or nonactivated VCPs. Additionally, these bond-breaking reactions can occur as intra- or intermolecular processes. The properties of activated and nonactivated VCPs are discussed in the Introduction. Various transition metal-catalyzed cycloaddition and addition reactions involving the cleavage of C-C bonds in activated VCPs are then discussed in the next chapter. The transition metal-catalyzed cycloadditions involving the cleavage of C-C in nonactivated VCPs are summarized in the following chapter. Finally, challenges and potential opportunities are outlined in the last chapter.
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Registered trials
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