Evidence map›Paper›PMID 32786130›Full record

ArticleChemistry (Weinheim an der Bergstrasse, Germany)2021

Beyond p-Hexaphenylenes: Synthesis of Unsubstituted p-Nonaphenylene by a Precursor Protocol.

Ali Abdulkarim, Marvin Nathusius, Rainer Bäuerle, Karl-Philipp Strunk, Sebastian Beck, Hans Joachim Räder, Annemarie Pucci, Christian Melzer, Daniel Jänsch, Jan Freudenberg and 2 more

Abstract read
In one paragraph

Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

  1. Synthesis and Properties of [3]Rotaxanes with Two Oligo(para-phenylene) Axles.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025
    Article
  2. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

12 authors.

Ali AbdulkarimOrganisch-Chemisches Institut, Ruprecht-Karls-Universität Heidelberg, Im Neuenheimer Feld 270, 69120, Heidelberg, Germany.
Marvin NathusiusOrganisch-Chemisches Institut, Ruprecht-Karls-Universität Heidelberg, Im Neuenheimer Feld 270, 69120, Heidelberg, Germany.
Rainer BäuerleInnovationLab, Speyerer Str. 4, 69115, Heidelberg, Germany.
Karl-Philipp StrunkKirchhoff-Institut für Physik, Ruprecht-Karls-Universität Heidelberg, Im Neuenheimer Feld 227, 69120, Heidelberg, Germany.
Sebastian BeckInnovationLab, Speyerer Str. 4, 69115, Heidelberg, Germany.
Hans Joachim RäderMax Planck Institute for Polymer Research, Ackermannweg 10, 55128, Mainz, Germany.
Annemarie PucciInnovationLab, Speyerer Str. 4, 69115, Heidelberg, Germany.
Christian MelzerInnovationLab, Speyerer Str. 4, 69115, Heidelberg, Germany.
Daniel JänschOrganisch-Chemisches Institut, Ruprecht-Karls-Universität Heidelberg, Im Neuenheimer Feld 270, 69120, Heidelberg, Germany.
Jan FreudenbergOrganisch-Chemisches Institut, Ruprecht-Karls-Universität Heidelberg, Im Neuenheimer Feld 270, 69120, Heidelberg, Germany.
Uwe H F BunzOrganisch-Chemisches Institut, Ruprecht-Karls-Universität Heidelberg, Im Neuenheimer Feld 270, 69120, Heidelberg, Germany.
Klaus MüllenMax Planck Institute for Polymer Research, Ackermannweg 10, 55128, Mainz, Germany.ORCID http://orcid.org/0000-0001-6630-8786

Funding

Bundesministerium für Bildung und Forschung FKZ 13N13657Bundesministerium für Bildung und Forschung FKZ 13N13695Studienstiftung des Deutschen VolkesUniversity Heidelberg Field of Focus 2
6 · The paper itself

Abstract

The synthesis of unsubstituted oligo-para-phenylenes (OPP) exceeding para-hexaphenylene-in the literature often referred to as p-sexiphenyl-has long remained elusive due to their insolubility. We report the first preparation of unsubstituted para-nonaphenylenes (9PPs) by extending our precursor route to poly-para-phenylenes (PPP) to a discrete oligomer. Two geometric isomers of methoxylated syn- and anti-cyclohexadienylenes were synthesized, from which 9PP was obtained via thermal aromatization in thin films. 9PP was characterized via optical, infrared and solid-state

Indexed as

conjugationoligo-para-phenylenepi interactionprecursor route

Identifiers

PMID32786130
PMCPMC7839583

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.