ArticleAngewandte Chemie (International ed. in English)2020
The Nature of Strong Chalcogen Bonds Involving Chalcogen-Containing Heterocycles.
Article in Angewandte Chemie (International ed. in English), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 24 papers.
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Who cites it
24 citing papers in PubMed, 106 citations in OpenAlex.
- Tuning σ‑Hole Chalcogen···Nitrogen Bonding Between CACS omega · 2026Article
- Visible light-induced single bond rotation in azoarenes triggered by self-sensitized oxidation.Chemical science · 2026Article
- Hierarchical on-surface assembly of nanoribbons through concurrent hydrogen- and chalcogen-bonding interactions.Chemical science · 2026Article
- Chalcogen bonding-directed photoresponsive helix from azo-fused H-bonded arylamide foldamers.Chemical science · 2026Article
- Electronic structure and tunability of pnictogen bonds in YH 3 and X-YH 3 (X = O, S; Y = N, P, As) systems.Journal of molecular modeling · 2026Article
- A Substrate-Dependent Redox Catalysis of Tellurenyl Species Involving Oxidation States +I, +II, and +IV.Inorganic chemistry · 2026Article
- Supramolecular 3D Polymers Created via Chalcogen Bonding Using Benzotellurazoles as Planar Recognition Units.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Chalcogen-Guided Control of Azoarene Photoswitching: Tuning Excited-State Energies Through Electronic Property Modulation.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Understanding Non-Covalent Interactions in Diphenyldiselenide and Diphenylselenide Cocrystals Using a CombinedThe journal of physical chemistry. C, Nanomaterials and interfaces · 2025Article
- Supramolecular Chalcogen-Bonded Shape Memory Actuators.Angewandte Chemie (International ed. in English) · 2025Article
- Effect of Chalcogen Interaction on the Structure of Methine-Bridged Trichalcogenophenes.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Article
- Phenotellurazine redox catalysts: elements of design for radical cross-dehydrogenative coupling reactions.Beilstein journal of organic chemistry · 2024Article
- Selection of isomerization pathways of multistep photoswitches by chalcogen bonding.Nature communications · 2023Article
- A Structural Approach to the Strength Evaluation of Linear Chalcogen Bonds.Molecules (Basel, Switzerland) · 2023Article
- Computational evaluation of halogen-bonded cocrystals enables prediction of their mechanochemical interconversion reactions.Chemical science · 2023Article
- Sulfur-mediated chalcogen versus hydrogen bonds in proteins: a see-saw effect in the conformational space.QRB discovery · 2023Article
- OJACS Au · 2022Article
- Predictability of Chalcogen-Bond-Driven Crystal Engineering: An X-ray Diffraction and Selenium-77 Solid-State NMR Investigation of Benzylic Selenocyanate Cocrystals.ACS organic & inorganic Au · 2022Article
- Te(II)-Catalyzed Cross-Dehydrogenative Phenothiazination of Anilines.Organic letters · 2022Article
Corrections and comments
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Authors and funding
2 authors at 2 institutions in 1 country.
Funding
Abstract
Chalcogen bonds are σ hole interactions and have been used in recent years as an alternative to hydrogen bonds. In general, the electrostatic potential at the chalcogen atom and orbital delocalization effects are made responsible for the orientation of the chalcogen bond. Here, we were able to show by means of SAPT calculations that neither the induction (orbital delocalization effects) nor the electrostatic term is causing the spatial orientation of strong chalcogen bonds in tellurium-containing aromatics. Instead, steric interactions (Pauli repulsion) are responsible for the orientation. Against chemical intuition the dispersion energies of the examined tellurium-containing aromatics are far less important for the net attractive forces compared to the energies in the corresponding sulfur and selenium compounds. Our results underline the importance of often overlooked steric interactions (Pauli repulsion) in conformational control of σ hole interactions.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.