Evidence map›Paper›PMID 32770682›Full record

ArticleChemistry (Weinheim an der Bergstrasse, Germany)2020

Recyclable Ruthenium Catalyst for Distal meta-C-H Activation.

Isaac Choi, Valentin Müller, Yanhui Wang, Kai Xue, Rositha Kuniyil, Loren B Andreas, Volker Karius, Johan G Alauzun, Lutz Ackermann

Erratum issuedAbstract read
In one paragraph

Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. An erratum has been issued. Cited by 8 papers.

0numbers the graph read from it
0cells of the map it votes in
8citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

8 citing papers in PubMed.

  1. Article
  2. Article
  3. Review
  4. Review
  5. Improving the sustainability of the ruthenium-catalysedGreen chemistry : an international journal and green chemistry resource : GC · 2023
    Article
  6. Article
  7. Article
  8. Recyclable Ruthenium Catalyst for Distal meta-C-H Activation.Chemistry (Weinheim an der Bergstrasse, Germany) · 2020
    Article
4 · The record

Corrections and comments

5 · Who and what money

Authors and funding

9 authors.

Isaac ChoiInstitut für Organische und Biomolekulare Chemie and, Wöhler Research Institute for Sustainable Chemistry (WISCh), Georg-August-Universität, Tammanstraße 2, 37077, Göttingen, Germany.ORCID http://orcid.org/0000-0002-9207-4845
Valentin MüllerInstitut für Organische und Biomolekulare Chemie and, Wöhler Research Institute for Sustainable Chemistry (WISCh), Georg-August-Universität, Tammanstraße 2, 37077, Göttingen, Germany.ORCID http://orcid.org/0000-0001-5406-3048
Yanhui WangInstitut Charles Gerhardt Montpellier, UMR 5253, CNRS-Université de Montpellier-ENSCM, Montpellier Cedex 5, 34095, France.
Kai XueMax Planck Institute for Biophysical Chemistry, Am Faßberg 11, 37077, Göttingen, Germany.
Rositha KuniyilInstitut für Organische und Biomolekulare Chemie and, Wöhler Research Institute for Sustainable Chemistry (WISCh), Georg-August-Universität, Tammanstraße 2, 37077, Göttingen, Germany.ORCID http://orcid.org/0000-0001-5480-3667
Loren B AndreasMax Planck Institute for Biophysical Chemistry, Am Faßberg 11, 37077, Göttingen, Germany.ORCID http://orcid.org/0000-0003-3216-9065
Volker KariusGeowissenschaftliches Zentrum, Georg-August-Universität Göttingen, Goldschmidtstraße 3, 37077, Göttingen, Germany.ORCID http://orcid.org/0000-0002-6396-0792
Johan G AlauzunInstitut Charles Gerhardt Montpellier, UMR 5253, CNRS-Université de Montpellier-ENSCM, Montpellier Cedex 5, 34095, France.ORCID http://orcid.org/0000-0002-6531-0750
Lutz AckermannInstitut für Organische und Biomolekulare Chemie and, Wöhler Research Institute for Sustainable Chemistry (WISCh), Georg-August-Universität, Tammanstraße 2, 37077, Göttingen, Germany.ORCID http://orcid.org/0000-0001-7034-8772

Funding

DFGHorizon 2020 Framework Programme 720996Kwanjeong Educational FoundationMax Planck Institute for Biophysical Chemistry
6 · The paper itself

Abstract

We disclose the unprecedented hybrid-ruthenium catalysis for distal meta-C-H activation. The hybrid-ruthenium catalyst was recyclable, as was proven by various heterogeneity tests, and fully characterized with various microscopic and spectroscopic techniques, highlighting the physical and chemical stability. Thereby, the hybrid-ruthenium catalysis proved broadly applicable for meta-C-H alkylations of among others purine-based nucleosides and natural product conjugates. Additionally, its versatility was further reflected by meta-C-H activations through visible-light irradiation, as well as para-selective C-H activations.

Indexed as

alkylationC−H activationheterogeneous catalysismeta-selectivityphotocatalysis

Identifiers

PMID32770682
PMCPMC7756437

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.