ArticleScience advances2020
Kilohertz electron paramagnetic resonance spectroscopy of single nitrogen centers at zero magnetic field.
Article in Science advances, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
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Who cites it
4 citing papers in PubMed.
- Sensing Spin Precession with Free Electrons.ACS nano · 2026Article
- A coherence-protection scheme for quantum sensors based on ultra-shallow single nitrogen-vacancy centers in diamond.Nature communications · 2025Article
- In situ electron paramagnetic resonance spectroscopy using single nanodiamond sensors.Nature communications · 2023Article
- CSRR Structure Design for NV Spin Manipulation with Microwave Strength and Fluorescence Collection Synchronous Enhancement.Materials (Basel, Switzerland) · 2023Article
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Authors and funding
9 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Electron paramagnetic resonance (EPR) spectroscopy is among the most important analytical tools in physics, chemistry, and biology. The emergence of nitrogen-vacancy (NV) centers in diamond, serving as an atomic-sized magnetometer, has promoted this technique to single-spin level, even under ambient conditions. Despite the enormous progress in spatial resolution, the current megahertz spectral resolution is still insufficient to resolve key heterogeneous molecular information. A major challenge is the short coherence times of the sample electron spins. Here, we address this challenge by using a magnetic noise-insensitive transition between states of different symmetry. We demonstrate a 27-fold narrower spectrum of single substitutional nitrogen (P1) centers in diamond with a linewidth of several kilohertz, and then some weak couplings can be resolved. Those results show both spatial and spectral advances of NV center-based EPR and provide a route toward analytical (EPR) spectroscopy at the single-molecule level.
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Registered trials
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