ReviewChemistry (Weinheim an der Bergstrasse, Germany)2021
Recent Perspectives on Rearrangement Reactions of Ylides via Carbene Transfer Reactions.
Review in Chemistry (Weinheim an der Bergstrasse, Germany), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 29 papers.
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Who cites it
29 citing papers in PubMed.
- The Catalytic Enantioselective Sommelet-Hauser Rearrangement.Journal of the American Chemical Society · 2026Article
- Sulfur-Directed Construction of Vinyl Cyclopropanes from 1,3-Dienes.Angewandte Chemie (International ed. in English) · 2026Article
- Alkynyltriazenes in Photochemical Metal-Free Doyle-Kirmse Rearrangements.Angewandte Chemie (International ed. in English) · 2026Article
- Transition Metal-Free Formal C─H/C─H Coupling of Arylacetamides and Sulfoxides: An Interrupted Pummerer/[2,3]-sigmatropic Rearrangement Sequence.Angewandte Chemie (International ed. in English) · 2025Article
- [2,3]-Sigmatropic rearrangement with [1.1.1]propellane.Nature communications · 2025Article
- Metal-Catalyzed Fluoroacetyl Carbene Transfer from Sulfonium Salts.Organic letters · 2025Article
- Ligand-controlled divergent asymmetric C(spNature communications · 2025Article
- Fe(OTf)3 or Photosensitizer-free blue light activated diazo-thioglycoside donors for Iterative and stereoselective glycosylations.Nature communications · 2025Article
- Dirhodium Complexes Heterochiral-at-the-Metal Centers: An Alternative Type of Paddlewheel Catalyst for Asymmetric Synthesis.Journal of the American Chemical Society · 2025Article
- Photoinduced C-Cl Bond Activation of Polychloroalkanes with Triplet Carbenes: Synthetic Applications and Mechanistic Studies.JACS Au · 2025Article
- Machine-Learning-Aided Engineering Hemoglobin as Carbene Transferase for Catalyzing Enantioselective Olefin Cyclopropanation.JACS Au · 2024Article
- Article
- Visible Light-Induced Reactions of Diazo Compounds and Their Precursors.Chemical reviews · 2024Review
- Tunable Divergent Reactivity of Aziridinium Ylides in the Synthesis of Complex Piperidines and Azetidines.ACS catalysis · 2024Article
- Electro-oxidative quinylation of sulfides to sulfur ylides in batch and continuous flow.iScience · 2024Article
- A highly diastereoselective strain-release Doyle-Kirmse reaction: access to functionalized difluoro(methylene)cyclopropanes.Chemical science · 2023Article
- Copper-catalyzed enantioselective diyne cyclizationChemical science · 2023Article
- Reshuffle Bonds by Ball Milling: A Mechanochemical Protocol for Charge-Accelerated Aza-Claisen Rearrangements.Molecules (Basel, Switzerland) · 2023Article
- Photochemical synthesis of 1,2,4-triazolesChemical science · 2022Article
- Recent advances in metal-catalysed asymmetric sigmatropic rearrangements.Chemical science · 2022Review
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Abstract
Among the available methods to increase the molecular complexity, sigmatropic rearrangements occupy a distinct position in organic synthesis. Despite being known for over a century sigmatropic rearrangement reactions of ylides via carbene transfer reaction have only recently come of age. Most of the ylide mediated rearrangement processes involve rupture of a σ-bond and formation of a new bond between π-bond and negatively charged atom followed by simultaneous redistribution of π-electrons. This minireview describes the advances in this research area made in recent years, which now opens up metal-catalyzed enantioselective sigmatropic rearrangement reactions, metal-free photochemical rearrangement reactions and novel reaction pathways that can be accessed via ylide intermediates.
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