Evidence map›Paper›PMID 32751133›Full record

ArticleMolecules (Basel, Switzerland)2020

Photoinduced Polymerization of Eugenol-Derived Methacrylates.

Samantha Molina-Gutiérrez, Sara Dalle Vacche, Alessandra Vitale, Vincent Ladmiral, Sylvain Caillol, Roberta Bongiovanni, Patrick Lacroix-Desmazes

Open access · goldAbstract read
In one paragraph

Article in Molecules (Basel, Switzerland), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.

0numbers the graph read from it
0cells of the map it votes in
10citing papers in PubMed
2.7field-weighted citation impact, top 9% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

10 citing papers in PubMed, 39 citations in OpenAlex.

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  10. Special Issue "Natural Polymers and Biopolymers II".Molecules (Basel, Switzerland) · 2020
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors at 2 institutions in 2 countries.

Samantha Molina-GutiérrezInstitut Charles Gerhardt Montpellier (ICGM), University of Montpellier, CNRS, ENSCM, 34095 Montpellier, France.
Sara Dalle VaccheDepartment of Applied Science and Technology, Politecnico di Torino, Corso Duca degli Abruzzi 24, 10129 Torino, Italy.ORCID 0000-0001-5459-5714
Alessandra VitaleDepartment of Applied Science and Technology, Politecnico di Torino, Corso Duca degli Abruzzi 24, 10129 Torino, Italy.ORCID 0000-0002-8682-3125
Vincent LadmiralInstitut Charles Gerhardt Montpellier (ICGM), University of Montpellier, CNRS, ENSCM, 34095 Montpellier, France.ORCID 0000-0002-7590-4800
Sylvain CaillolInstitut Charles Gerhardt Montpellier (ICGM), University of Montpellier, CNRS, ENSCM, 34095 Montpellier, France.ORCID 0000-0003-3106-5547
Roberta BongiovanniDepartment of Applied Science and Technology, Politecnico di Torino, Corso Duca degli Abruzzi 24, 10129 Torino, Italy.ORCID 0000-0002-2607-9461
Patrick Lacroix-DesmazesInstitut Charles Gerhardt Montpellier (ICGM), University of Montpellier, CNRS, ENSCM, 34095 Montpellier, France.ORCID 0000-0002-0197-7062
École Nationale Supérieure de Chimie de Montpellier · FRPolitecnico di Torino · IT

Funding

H2020 Marie Skłodowska-Curie Actions no. 789454SINCHEM FPA 2013-0037
6 · The paper itself

Abstract

Biobased monomers have been used to replace their petroleum counterparts in the synthesis of polymers that are aimed at different applications. However, environmentally friendly polymerization processes are also essential to guarantee greener materials. Thus, photoinduced polymerization, which is low-energy consuming and solvent-free, rises as a suitable option. In this work, eugenol-, isoeugenol-, and dihydroeugenol-derived methacrylates are employed in radical photopolymerization to produce biobased polymers. The polymerization is monitored in the absence and presence of a photoinitiator and under air or protected from air, using Real-Time Fourier Transform Infrared Spectroscopy. The polymerization rate of the methacrylate double bonds was affected by the presence and reactivity of the allyl and propenyl groups in the eugenol- and isoeugenol-derived methacrylates, respectively. These groups are involved in radical addition, degradative chain transfer, and termination reactions, yielding crosslinked polymers. The materials, in the form of films, are characterized by differential scanning calorimetry, thermogravimetric, and contact angle analyses.

Indexed as

LightEugenolMethacrylatesMolecular StructurePolymerizationSpectrum AnalysisThermogravimetryEugenolMethacrylatesbiobased monomereugenol-derived methacrylatephotoinduced-polymerization

Identifiers

PMID32751133
PMCPMC7435665
OpenAlexW3046022838

What OpenQuestion holds

Textmetadata
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Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.