ReviewACS central science2020
Beyond Carbon: Enantioselective and Enantiospecific Reactions with Catalytically Generated Boryl- and Silylcopper Intermediates.
Review in ACS central science, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 22 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
22 citing papers in PubMed.
- Stereocontrolled entry to borylated piperidinesChemical science · 2026Article
- Enantioselective Miyaura Reaction by Desymmetrizing C(spAngewandte Chemie (International ed. in English) · 2025Article
- Switchable electrochemical pathways for the selective C(spNature communications · 2025Article
- Asymmetric Synthesis of Propargylic and Allenic Silanes, Germanes, and Stannanes.Chemistry, an Asian journal · 2025Review
- Recent advances and perspectives in synthetic applications of silylboronates as silyl radical precursors.Chemical science · 2025Review
- The role of silicon in drug discovery: a review.RSC medicinal chemistry · 2024Review
- Organocatalytic Asymmetric Allylic Benzylborylation via Fluoride-Assisted Catalytic Generation of α-Boryl Carbanionic Intermediates.Organic letters · 2024Article
- Enantioselective Aminosilylation of Alkenes by Palladium/Ming-Phos-Catalyzed Tandem Narasaka-Heck/Silylation Reaction.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
- Copper-catalyzed yne-allylic substitutions: concept and recent developments.Beilstein journal of organic chemistry · 2024Review
- Updated Progress of the Copper-Catalyzed Borylative Functionalization of Unsaturated Molecules.Molecules (Basel, Switzerland) · 2023Review
- Copper-Catalyzed Highly Enantioselective Addition of a Silicon Nucleophile to 3-Substituted 2H-Azirines Using an Si-B Reagent.Angewandte Chemie (International ed. in English) · 2023Article
- Boosting the Enantioselectivity of Conjugate Borylation of α,β-Disubstituted Cyclobutenones with Monooxides of Chiral CChemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Copper catalyzed borocarbonylation of benzylidenecyclopropanes through selective proximal C-C bond cleavage: synthesis of γ-boryl-γ,δ-unsaturated carbonyl compounds.Chemical science · 2022Article
- Sodium silylsilanolate as a precursor of silylcopper species.Chemical science · 2022Article
- Synthesis of Silylated Cyclobutanone and Cyclobutene Derivatives Involving 1,4-Addition of Zinc-Based Silicon Nucleophiles.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- Catalytic Arylboration of Spirocyclic Cyclobutenes: Rapid Access to Highly Substituted Spiro[3.n]alkanes.ACS catalysis · 2021Article
- Regioselective Monoborylation of Spirocyclobutenes.Organic letters · 2021Article
- Synthesis of hydrosilylboronatesChemical science · 2021Article
- Modular Synthesis of a Versatile Double-Allylation Reagent for Complex Diol Synthesis.Angewandte Chemie (International ed. in English) · 2021Article
- Construction of congested CspChemical science · 2021Article
Corrections and comments
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Authors and funding
2 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Catalytic asymmetric C-C bond formation with alkylcopper intermediates as carbon nucleophiles is now textbook chemistry. Related chemistry with boron and silicon nucleophiles where the boryl- and accordingly silylcopper intermediates are catalytically regenerated from bench-stable pronucleophiles had been underdeveloped for years or did not even exist until recently. Over the past decade, asymmetric copper catalysis employing those main-group elements as nucleophiles rapidly transformed into a huge field in its own right with an impressive breadth of enantioselective C-B and C-Si bond-forming reactions, respectively. Its current state of the art does not have to shy away from comparison with that of boron's and silicon's common neighbor in the periodic table, carbon. This Outlook is not meant to be a detailed summary of those manifold advances. It rather aims at providing a brief conceptual summary of what forms the basis of the latest exciting progress, especially in the area of three-component reactions and cross-coupling reactions.
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Registered trials
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