ArticleNanomaterials (Basel, Switzerland)2020
Electrodeposition of Mesoporous Ni-Rich Ni-Pt Films for Highly Efficient Methanol Oxidation.
Article in Nanomaterials (Basel, Switzerland), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
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Who cites it
6 citing papers in PubMed, 16 citations in OpenAlex.
- Sputtered Cu-doped NiO thin films as an efficient electrocatalyst for methanol oxidation.RSC advances · 2023Article
- Roles of TOPO Coordinating Solvent on Prepared Nano-Flower/Star and Nano-Rods Nickel Sulphides for Solar Cells Applications.Nanomaterials (Basel, Switzerland) · 2022Article
- Impedance Spectroscopic Study of Nickel Sulfide Nanostructures Deposited by Aerosol Assisted Chemical Vapor Deposition Technique.Nanomaterials (Basel, Switzerland) · 2021Article
- Electrodeposited Ni-Rich Ni-Pt Mesoporous Nanowires for Selective and Efficient Formic Acid-Assisted Hydrogenation of Levulinic Acid to γ-Valerolactone.Langmuir : the ACS journal of surfaces and colloids · 2021Article
- Article
- Synthesis and Characterization of Ni-Pt Alloy Thin Films Prepared by Supercritical Fluid Chemical Deposition Technique.Nanomaterials (Basel, Switzerland) · 2021Article
Corrections and comments
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Authors and funding
5 authors at 2 institutions in 2 countries.
Funding
Abstract
The use of soft templates for the electrosynthesis of mesoporous materials has shown tremendous potential in energy and environmental domains. Among all the approaches that have been featured in the literature, block copolymer-templated electrodeposition had robustness and a simple method, but it practically cannot be used for the synthesis of mesoporous materials not based on Pt or Au. Nonetheless, extending and understanding the possibilities and limitations of block copolymer-templated electrodeposition to other materials and substrates is still challenging. Herein, a critical analysis of the role of the solution's primary electroactive components and the applied potential were performed in order to understand their influences on the mesostructure of Ni-rich Ni-Pt mesoporous films. Among all the components, tetrahydrofuran and a platinum (IV) complex were shown to be crucial for the formation of a truly 3D mesoporous network. The electrosynthesized well-ordered mesoporous Ni-rich Ni-Pt deposits exhibit excellent electrocatalytic performance for methanol oxidation in alkaline conditions, improved stability and durability after 1000 cycles, and minimal CO poisoning.
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