Evidence map›Paper›PMID 32708013›Full record

ArticleMolecules (Basel, Switzerland)2020

High-Silica Zeolites as Sorbent Media for Adsorption and Pre-Concentration of Pharmaceuticals in Aqueous Solutions.

Elena Sarti, Tatiana Chenet, Claudia Stevanin, Valentina Costa, Alberto Cavazzini, Martina Catani, Annalisa Martucci, Nicola Precisvalle, Giada Beltrami, Luisa Pasti

Open access · goldAbstract read
In one paragraph

Article in Molecules (Basel, Switzerland), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.

0numbers the graph read from it
0cells of the map it votes in
6citing papers in PubMed
1.9field-weighted citation impact, top 17% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

6 citing papers in PubMed, 24 citations in OpenAlex.

  1. Review
  2. Review
  3. Article
  4. Article
  5. Hemoperfusion: technical aspects and state of the art.Critical care (London, England) · 2022
    Review
  6. Zeolitic Microporous Materials and Their Applications.Molecules (Basel, Switzerland) · 2021
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

10 authors at 1 institution in 1 country.

Elena SartiDepartment of Chemical and Pharmaceutical Sciences, University of Ferrara, Via Luigi Borsari 46, 44121 Ferrara, Italy.
Tatiana ChenetDepartment of Chemical and Pharmaceutical Sciences, University of Ferrara, Via Luigi Borsari 46, 44121 Ferrara, Italy.
Claudia StevaninDepartment of Chemical and Pharmaceutical Sciences, University of Ferrara, Via Luigi Borsari 46, 44121 Ferrara, Italy.
Valentina CostaDepartment of Chemical and Pharmaceutical Sciences, University of Ferrara, Via Luigi Borsari 46, 44121 Ferrara, Italy.ORCID 0000-0001-8188-831X
Alberto CavazziniDepartment of Chemical and Pharmaceutical Sciences, University of Ferrara, Via Luigi Borsari 46, 44121 Ferrara, Italy.
Martina CataniDepartment of Chemical and Pharmaceutical Sciences, University of Ferrara, Via Luigi Borsari 46, 44121 Ferrara, Italy.
Annalisa MartucciDepartment of Physics and Earth Sciences, University of Ferrara, Via Giuseppe Saragat 1, 44122 Ferrara, Italy.
Nicola PrecisvalleDepartment of Physics and Earth Sciences, University of Ferrara, Via Giuseppe Saragat 1, 44122 Ferrara, Italy.ORCID 0000-0002-0727-2434
Giada BeltramiDepartment of Physics and Earth Sciences, University of Ferrara, Via Giuseppe Saragat 1, 44122 Ferrara, Italy.
Luisa PastiDepartment of Chemical and Pharmaceutical Sciences, University of Ferrara, Via Luigi Borsari 46, 44121 Ferrara, Italy.ORCID 0000-0002-2980-3654
University of Ferrara · IT

Funding

Interreg Project: PEPSEA (ID number 10047424)Ministero dell'Istruzione, dell'Università e della Ricerca 2017Y2PAB8_003
6 · The paper itself

Abstract

The present work focused on the use of high-silica commercial zeolites as sorbent media for pharmaceuticals in an aqueous matrix. As drug probes, ketoprofen, hydrochlorothiazide, and atenolol were selected, because of their occurrence in surface waters and effluents from wastewater treatment plants. Pharmaceuticals adsorption was evaluated for two Faujasite topology zeolites with Silica/Alumina Ratio 30 and 200. The selected zeolites were demonstrated to be efficient sorbents towards all investigated pharmaceuticals, thanks to their high saturation capacities (from 12 to 32% w/w) and binding constants. These results were corroborated by thermal and structural analyses, which revealed that adsorption occurred inside zeolite's porosities, causing lattice modifications. Finally, zeolites have been tested as a pre-concentration media in the dispersive-solid phase extraction procedure. Recoveries higher than 95% were gained for ketoprofen and hydrochlorothiazide and approximately 85% for atenolol, at conditions that promoted the dissolution of the neutral solute into a phase mainly organic. The results were obtained by using a short contact time (5 min) and reduced volume of extraction (500 µL), without halogenated solvents. These appealing features make the proposed procedure a cost and time saving method for sample enrichment as well as for the regeneration of exhausted sorbent, rather than the more energetically expensive thermal treatment.

Indexed as

AdsorptionAtenololHydrochlorothiazideKetoprofenPorositySilicon DioxideSolid Phase ExtractionSolventsSurface PropertiesWaterWater Pollutants, ChemicalZeolitesAtenololHydrochlorothiazideKetoprofenSilicon DioxideSolventsWaterWater Pollutants, ChemicalZeolitesadsorptionemerging contaminantspre-concentrationsorbent regenerationzeolites

Identifiers

PMID32708013
PMCPMC7436148
OpenAlexW3044840786

What OpenQuestion holds

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LicenceCC BY
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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.