ArticleACS nano2020
Exploiting the Surface Properties of Graphene for Polymorph Selectivity.
Article in ACS nano, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.
What it found
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Who cites it
8 citing papers in PubMed, 21 citations in OpenAlex.
- Interface-Induced Concentration Enhancement in Glycine Solutions Investigated Using Surface Plasmon Resonance Spectroscopy and Molecular Dynamics Simulations.The journal of physical chemistry letters · 2026Article
- A tailored graphene supramolecular gel for pharmaceutical crystallization.Chemical science · 2025Article
- Crystallization of molecular layers produced under confinement onto a surface.Nature communications · 2024Article
- Tuning Interfacial Concentration Enhancement through Dispersion Interactions to Facilitate Heterogeneous Nucleation.The journal of physical chemistry. C, Nanomaterials and interfaces · 2022Article
- Adsorptive separation using self-assembly on graphite: from nanoscale to bulk processes.Chemical science · 2022Article
- Electrolyte-Gated Organic Field-Effect Transistors for Quantitative Monitoring of the Molecular Dynamics of Crystallization at the Solid-Liquid Interface.Nano letters · 2022Article
- Selective Crystallization of d-Mannitol Polymorphs Using Surfactant Self-Assembly.Crystal growth & design · 2021Article
- Real-time monitoring of crystallization from solution by using an interdigitated array electrode sensor.Nanoscale horizons · 2021Article
Corrections and comments
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Authors and funding
7 authors at 2 institutions in 2 countries.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Producing crystals of the desired form (polymorph) is currently a challenge as nucleation is yet to be fully understood. Templated crystallization is an efficient approach to achieve polymorph selectivity; however, it is still unclear how to design the template to achieve selective crystallization of specific polymorphs. More insights into the nanoscale interactions happening during nucleation are needed. In this work, we investigate crystallization of glycine using graphene, with different surface chemistry, as a template. We show that graphene induces the preferential crystallization of the metastable α-polymorph compared to the unstable β-form at the contact region of an evaporating droplet. Computer modeling indicates the presence of a small amount of oxidized moieties on graphene to be responsible for the increased stabilization of the α-form. In conclusion, our work shows that graphene could become an attractive material for polymorph selectivity and screening by exploiting its tunable surface chemistry.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.