ArticleAngewandte Chemie (International ed. in English)2020
Solvent-Activated Hafnium-Containing Zeolites Enable Selective and Continuous Glucose-Fructose Isomerisation.
Article in Angewandte Chemie (International ed. in English), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.
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Who cites it
7 citing papers in PubMed, 50 citations in OpenAlex.
- Metal-Coordinated Lignosulfonate Catalysts for the Selective Conversion of Hexose: Active Site and Reaction Medium.Materials (Basel, Switzerland) · 2025Article
- Tracking Lattice Distortion Induced by Defects and Framework Tin in Beta Zeotypes.The journal of physical chemistry. C, Nanomaterials and interfaces · 2023Article
- Conversion of Similar Xenochemicals to Dissimilar Products: Exploiting Competing Reactions in Whole-Cell Catalysis.Molecules (Basel, Switzerland) · 2023Article
- From crystal phase mixture to pure metal-organic frameworks - Tuning pore and structure properties.Ultrasonics sonochemistry · 2023Article
- Effects of Acid Modulators on the Microwave-Assisted Synthesis of Cr/Sn Metal-Organic Frameworks.Polymers · 2022Article
- Tailoring Lewis/Brønsted acid properties of MOF nodesChemical science · 2021Article
- Solvent-Activated Hafnium-Containing Zeolites Enable Selective and Continuous Glucose-Fructose Isomerisation.Angewandte Chemie (International ed. in English) · 2020Article
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Authors and funding
7 authors at 5 institutions in 2 countries.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The isomerisation of glucose to fructose is a critical step towards manufacturing petroleum-free chemicals from lignocellulosic biomass. Herein we show that Hf-containing zeolites are unique catalysts for this reaction, enabling true thermodynamic equilibrium to be achieved in a single step during intensified continuous operation, which no chemical or biological catalyst has yet been able to achieve. Unprecedented single-pass yields of 58 % are observed at a fructose selectivity of 94 %, and continuous operation for over 100 hours is demonstrated. The unexpected performance of the catalyst is realised following a period of activation within the reactor, during which time interaction with the solvent generates a state of activity that is absent in the synthesised catalyst. Mechanistic studies by X-ray absorption spectroscopy, chemisorption FTIR, operando UV/Vis and
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