ArticleNature communications2020
Supramolecular double-stranded Archimedean spirals and concentric toroids.
Article in Nature communications, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 37 papers.
What it found
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Who cites it
37 citing papers in PubMed.
- Light-regulated templated self-assembly of bilayered nanotoroids.Chemical science · 2026Article
- Noncovalent synthesis of higher-order super-heterostructures from structurally distinct molecular π-systems via secondary nucleation.Nature communications · 2026Article
- Curvature-emergent supramolecular polymerization of a porphyrin dyad with a scissor-shaped motif.Chemical science · 2026Article
- Facial Asymmetry in the Helical Grooves of Chiral Helical Polymers to Create 2D Single-Chain Archimedean Spiral Nanostructures.ACS nano · 2025Article
- Supramolecular Polymorphism of the Hydrogen-BondedJournal of the American Chemical Society · 2025Article
- Molecular-level insights into the supramolecular gelation mechanism of urea derivative.Nature communications · 2025Article
- Secondary nucleation as a strategy towards hierarchically organized mesoscale topologies in supramolecular polymerization.Nature chemistry · 2025Review
- Coaxial Helices in Chiral Supramolecular Aggregates from Highly Hindered Chiral Allenes.Angewandte Chemie (International ed. in English) · 2025Article
- Chirality Evolution of Supramolecular Helices by Electron Transfer Assisted Secondary Nucleation.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- Secondary nucleation guided noncovalent synthesis of dendritic homochiral superstructures via growth on and from surface.Nature communications · 2024Article
- Pathway control in metallosupramolecular polymerization of a monoalkynylplatinum(ii) terpyridine complex through competitive complex formation.Chemical science · 2024Article
- Light-controlled smart materials: Supramolecular regulation and applications.Smart molecules : open access · 2024Review
- Logarithmic and Archimedean organic crystalline spirals.Nature communications · 2024Article
- Nanostructural diversity: self-assembly of isomeric pyrene-cholane amphiphiles into sheets, tubes, and worm-like morphologies.RSC advances · 2024Article
- Pathway-dependent supramolecular polymerization by planarity breaking.Chemical science · 2024Article
- Archimedean Spirals with Controllable Chirality: Disk Substrate-Mediated Solution Assembly of Rod-Coil Block Copolymers.JACS Au · 2024Article
- Noncovalent synthesis of homo and hetero-architectures of supramolecular polymers via secondary nucleation.Nature communications · 2024Article
- Supramolecular copolymerization of hydrophobic and hydrophilic monomers in liquid crystalline media.Chemical science · 2024Article
- Self-assembly of cyclic peptide monolayers by hydrophobic supramolecular hinges.Chemical science · 2023Article
- Controlling Helical Asymmetry in Supramolecular Copolymers byJournal of the American Chemical Society · 2023Article
Corrections and comments
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Authors and funding
14 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Connecting molecular-level phenomena to larger scales and, ultimately, to sophisticated molecular systems that resemble living systems remains a considerable challenge in supramolecular chemistry. To this end, molecular self-assembly at higher hierarchical levels has to be understood and controlled. Here, we report unusual self-assembled structures formed from a simple porphyrin derivative. Unexpectedly, this formed a one-dimensional (1D) supramolecular polymer that coiled to give an Archimedean spiral. Our analysis of the supramolecular polymerization by using mass-balance models suggested that the Archimedean spiral is formed at high concentrations of the monomer, whereas other aggregation types might form at low concentrations. Gratifyingly, we discovered that our porphyrin-based monomer formed supramolecular concentric toroids at low concentrations. Moreover, a mechanistic insight into the self-assembly process permitted a controlled synthesis of these concentric toroids. This study both illustrates the richness of self-assembled structures at higher levels of hierarchy and demonstrates a topological effect in noncovalent synthesis.
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Registered trials
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